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Molecules 2001, 6(11), 875-880; doi:10.3390/61100875

One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the Oxidant

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, Banacha 1, PL 02-097 Warsaw, Poland
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Received: 27 September 2001 / Revised: 11 October 2001 / Accepted: 12 October 2001 / Published: 31 October 2001
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Abstract

This paper reports a one-pot synthesis of the title bromides from both activated and deactivated iodoarenes which are first oxidized with anhydrous NaBO3·H2O/Ac2O/conc.H2SO4 liquid mixtures, then coupled in situ with benzene and activated arenes and, finally, precipitated out with a KBr solution; this method is easy, cheap, safe and fairly effective. View Full-Text
Keywords: diaryliodonium bromides; iodoarenes; arenes; sodium perborate as oxidant diaryliodonium bromides; iodoarenes; arenes; sodium perborate as oxidant
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Kryska, A.; Skulski, L. One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the Oxidant. Molecules 2001, 6, 875-880.

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