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Molecules 2001, 6(11), 869-874; doi:10.3390/61100869
Article

One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant

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Received: 27 September 2001 / Revised: 11 October 2001 / Accepted: 12 October 2001 / Published: 31 October 2001
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Abstract

Ten representative (dichloroiodo)arenes, ArICl2, were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I2/CrO3/AcOH/Ac2O/conc. H2SO4, followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl2 are useful in organic synthesis as mild and selective chlorinating and/or oxidizing agents.
Keywords: (dichloroiodo)arenes; arenes; diiodine; chromium(VI) oxide as oxidant (dichloroiodo)arenes; arenes; diiodine; chromium(VI) oxide as oxidant
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Obeid, N.; Skulski, L. One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant. Molecules 2001, 6, 869-874.

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