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Molecules 1999, 4(3), 69-72; doi:10.3390/40300069
Article

Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

1,* , 2
,
1 and 1
1 Current address: Department of Chemistry, The City College of CUNY, Convent Avenue at 138th Street, New York, NY 10031, USA 2 Current address: Department of Chemistry and Environmental Engineering, Beijing Polytechnic University, Beijing 100022, P. R. China
* Author to whom correspondence should be addressed.
Received: 12 May 1998 / Accepted: 5 March 1999 / Published: 16 March 1999
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Abstract

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyrazine dinitrate (2).
Keywords: Oxidative cleavage; hexabenzylhexaazaisowurtzitane; iminium cation Oxidative cleavage; hexabenzylhexaazaisowurtzitane; iminium cation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Guan, X.-P.; Yan, H.; Sun, J.-G.; Yu, Y.-Z. Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6. Molecules 1999, 4, 69-72.

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