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Table of Contents

Molecules, Volume 4, Issue 3 (March 1999), Pages 62-80

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	p. 62-68 Tae Woo Kwon, Sung Kee Chung and Michael B. Smith Article: Mass Spectra of 2-Substituted Diethyl Malonate Derivatives Molecules 1999, 4(3), 62-68; doi:10.3390/40300062 Received: 16 March 1998 / Accepted: 10 July 1998 / Published: 16 March 1999 Show/Hide Abstract | Download PDF Full-text (40 KB) Abstract: Addition of Grignard derivatives to diethyl ethoxymethylene malonate generates 2-substituted diethyl malonate derivatives. This paper reports the mass spectral data for these derivatives.
	p. 69-72 Xiao-Pei Guan, Hong Yan, Jian-Guang Sun and Yong-Zhong Yu Article: Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6 Molecules 1999, 4(3), 69-72; doi:10.3390/40300069 Received: 12 May 1998 / Accepted: 5 March 1999 / Published: 16 March 1999 Show/Hide Abstract | Download PDF Full-text (25 KB) Abstract: Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyrazine dinitrate (2).
	p. 73-80 Eva Sidoova, Katarina Kralova and Dusan Loos Article: 3-(2-Alkylsulfanyl-6-benzothiazolylaminomethyl)-2-benzoxazolethiones - Synthesis and Photosynthesis-Inhibiting Activity in Spinach Chloropasts Molecules 1999, 4(3), 73-80; doi:10.3390/40300073 Received: 12 May 1998 / Accepted: 5 March 1999 / Published: 29 March 1999 Show/Hide Abstract | Download PDF Full-text (31 KB) Abstract: The synthesis and photosynthesis-inhibiting activity of 14 new 3-(2-alkylsulfanyl-6-benzothiazolylaminomethyl)-2-benzoxazolethiones are reported. The new compounds were prepared by the reaction of 2-alkylsulfanyl-6-aminobenzothiazoles with 3-hydroxymethyl-2-benzoxazolethione. The structures of the compounds were verified by 1H NMR spectra. The compounds inhibit photosynthetic electron transport in spinach chloroplasts. The photosynthetic activity was found to depend on the calculated lipophilicity of the new compounds. Some structure characteristics and quantum chemical parameters were calculated by AM1 method.
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