High-Density Energetic Metal–Organic Frameworks Based on the 5,5′-Dinitro-2H,2′H-3,3′-bi-1,2,4-triazole
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis of Energetic Complexes
2.2. X-ray Crystallography
2.3. Ultraviolet-Visible (UV) Absorption
2.4. Stability and Detonation Properties
3. Experimental Materials and Methods
3.1. Chemical and Materials
3.2. Preparation of Ligands
3.3. Synthesis of the Energetic Metal Organic Framework
3.4. Measurement of Solid-State Ultraviolet Absorption
3.5. Measurement of Temperature Using Differential Scanning Calorimetry Measurement/Thermogravimetric
3.6. Measurement of Sensitivity
3.7. Measurement of Single-Crystal X-ray Diffraction
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample Availability: Samples of the compounds (5,5′-dinitro-2H,2H′-3,3′-bi-1,2,4-triazole, 5,5′-dinitro-3,3′-bis-1,2,4-triazole-1-diol, 4,4′-azo-1,2,4-triazole) are available from the authors. |
[∆n = ∆ni (products, g) − ∆nj (reactants, g), ∆ni or ∆nj is the total molar amount of gases in the products or reactnts]
MOF(DNBT)
MOF(DNBTO)
Compound | Tdec a | ρ b | N c | Ωco d | ISe | FS f | −Q g | P h | D i |
---|---|---|---|---|---|---|---|---|---|
1 | 323.2 | 1.93 | 52.44 | −26.97 | >40 | >360 | 4346.2 | 25.27 | 7.7 |
2 | 333.3 | 1.96 | 44.79 | −16.73 | 18 | 360 | 4476 | 27.62 | 7.86 |
[Cu(ATZ)(ClO4)2]n [34] | >250 | 1.40 | 32.66 | −13.35 | 1 | 8.8 | - | - | 6.5 |
[Cu(Pn)(N3)2]n [17] | 215.7 | 1.76 | 50.54 | −57.73 | 2.55 | - | - | - | - |
[Cu2(En)2(N3)4]n [35] | 201.8 | 1.93 | 53.95 | −46.22 | 7.84 | - | - | - | - |
[Cu(ATRZ)3(NO3)2]n [20] | 243 | 1.68 | 53.35 | −28.24 | 22.5 | 112 | 4388 | 35.68 | 9.16 |
[Cu(Htztr)2(H2O)2]n [36] | 345 | 1.89 | 52.72 | −34.43 | >40 | >360 | - | 30.57 | 8.18 |
RDX [12] | 210 | 1.8 | 37.84 | 0 | 7.5 | 120 | 1258.3 | 33.92 | 8.6 |
TNT` [12] | 244 | 1.65 | 18.50 | −24.7 | 15 | 353 | 852 | 20.50 | 7.178 |
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Dong, Y.; Peng, P.; Hu, B.; Su, H.; Li, S.; Pang, S. High-Density Energetic Metal–Organic Frameworks Based on the 5,5′-Dinitro-2H,2′H-3,3′-bi-1,2,4-triazole. Molecules 2017, 22, 1068. https://doi.org/10.3390/molecules22071068
Dong Y, Peng P, Hu B, Su H, Li S, Pang S. High-Density Energetic Metal–Organic Frameworks Based on the 5,5′-Dinitro-2H,2′H-3,3′-bi-1,2,4-triazole. Molecules. 2017; 22(7):1068. https://doi.org/10.3390/molecules22071068
Chicago/Turabian StyleDong, Yalu, Panpan Peng, Baoping Hu, Hui Su, Shenghua Li, and Siping Pang. 2017. "High-Density Energetic Metal–Organic Frameworks Based on the 5,5′-Dinitro-2H,2′H-3,3′-bi-1,2,4-triazole" Molecules 22, no. 7: 1068. https://doi.org/10.3390/molecules22071068