Rearrangements of Cycloalkenyl Aryl Ethers
AbstractRearrangement reactions of cycloalkenyl phenol and naphthyl ethers and the acid-catalyzed cyclization of the resulting product were investigated. Claisen rearrangement afforded 2-substituted phenol and naphthol derivatives. Combined Claisen and Cope rearrangement resulted in the formation of 4-substituted phenol and naphthol derivatives. In the case of cycloocthylphenyl ether the consecutive Claisen and Cope rearrangements were followed by an alkyl migration. The mechanism of this novel rearrangement reaction is also discussed. View Full-Text
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Törincsi, M.; Nagy, M.; Bihari, T.; Stirling, A.; Kolonits, P.; Novak, L. Rearrangements of Cycloalkenyl Aryl Ethers. Molecules 2016, 21, 503.
Törincsi M, Nagy M, Bihari T, Stirling A, Kolonits P, Novak L. Rearrangements of Cycloalkenyl Aryl Ethers. Molecules. 2016; 21(4):503.Chicago/Turabian Style
Törincsi, Mercedesz; Nagy, Melinda; Bihari, Tamás; Stirling, András; Kolonits, Pál; Novak, Lajos. 2016. "Rearrangements of Cycloalkenyl Aryl Ethers." Molecules 21, no. 4: 503.
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