Heterogeneous Phase Microwave-Assisted Reactions under CO2 or CO Pressure
Abstract
:1. Introduction
2. MW-Assisted Reactions under CO2 Pressure
3. MW-Assisted Reactions under CO Pressure
4. A Promising Future for the Use of MW-Assisted Protocols under CO2 or CO Pressure
5. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Entry | Catalytic System | MW (Watt) | Temp. (°C) | CO2 (bar) | Time (min) | Yield (%) | Conv. (%) | Ref. |
---|---|---|---|---|---|---|---|---|
1 | [C6MIm]Br (0.05 mol %) | / | 140 | 10 | 60 | 86 | 97 | [56] |
2 | ZnPO (0.043 mol %), C4NBr (2.174 mol %) | 300 | 120 | 30 | 60 | 97 | / | [58] |
3 | TABC (0.027 mol %) | 200 | 120–160 | 9.7 | 30 | 91.4 | / | [59] |
4 | SiO2/C4ImBr (4 wt %) | 100 | 120–160 | 9.7 | 15 | 87.9 | / | [59] |
5 | HCOOH (0.145 mol %), KI (0.016 mol %) | 200 | / | 9.6 | 15 | 59 | 60 | [62] |
6 | C4PyBr (0.054 mol %) | 200 | 0-180 | 9.6 | 0.5 | 67.2 | 70 | [63] |
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Calcio Gaudino, E.; Rinaldi, L.; Rotolo, L.; Carnaroglio, D.; Pirola, C.; Cravotto, G. Heterogeneous Phase Microwave-Assisted Reactions under CO2 or CO Pressure. Molecules 2016, 21, 253. https://doi.org/10.3390/molecules21030253
Calcio Gaudino E, Rinaldi L, Rotolo L, Carnaroglio D, Pirola C, Cravotto G. Heterogeneous Phase Microwave-Assisted Reactions under CO2 or CO Pressure. Molecules. 2016; 21(3):253. https://doi.org/10.3390/molecules21030253
Chicago/Turabian StyleCalcio Gaudino, Emanuela, Laura Rinaldi, Laura Rotolo, Diego Carnaroglio, Camillo Pirola, and Giancarlo Cravotto. 2016. "Heterogeneous Phase Microwave-Assisted Reactions under CO2 or CO Pressure" Molecules 21, no. 3: 253. https://doi.org/10.3390/molecules21030253