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Molecules 2015, 20(5), 8020-8032; doi:10.3390/molecules20058020

Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

1
Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany
2
Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania
These authors contributed equally to this work.
*
Author to whom correspondence should be addressed.
Academic Editor: Dong-Sheng Li
Received: 29 March 2015 / Revised: 23 April 2015 / Accepted: 28 April 2015 / Published: 4 May 2015
(This article belongs to the Special Issue Metal-Organic Frameworks: Chemistry and Applications)
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Abstract

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)22S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques. View Full-Text
Keywords: 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid; silver(I) complex; mixed Ag-Cd coordination polymer 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid; silver(I) complex; mixed Ag-Cd coordination polymer
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Grosu, I.G.; Berghof, C.; Lönnecke, P.; Silaghi-Dumitrescu, L.; Hey-Hawkins, E. Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer. Molecules 2015, 20, 8020-8032.

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