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Molecules 2015, 20(4), 6683-6699; doi:10.3390/molecules20046683

Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs

1
Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain
2
Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain
3
BCMaterials, Parque Tecnológico de Zamudio, Ibaizabal Bidea, Edificio 500-Planta 1, 48160 Derio, Spain
*
Author to whom correspondence should be addressed.
Academic Editor: Dong-Sheng Li
Received: 5 February 2015 / Revised: 9 March 2015 / Accepted: 8 April 2015 / Published: 15 April 2015
(This article belongs to the Special Issue Metal-Organic Frameworks: Chemistry and Applications)
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Abstract

Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities. View Full-Text
Keywords: metalloporphyrin; Solid Coordination Frameworks (SCFs); crystal structure; dimensionality metalloporphyrin; Solid Coordination Frameworks (SCFs); crystal structure; dimensionality
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Fidalgo-Marijuan, A.; Amayuelas, E.; Barandika, G.; Bazán, B.; Urtiaga, M.K.; Arriortua, M.I. Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs. Molecules 2015, 20, 6683-6699.

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