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Molecules 2014, 19(10), 15891-15899; doi:10.3390/molecules191015891

Photochemical Aryl Radical Cyclizations to Give (E)-3-Ylideneoxindoles

1
School of Chemistry, National University of Ireland Galway, University Road, Galway, Ireland
2
Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims-Champagne-Ardenne, Faculté de Pharmacie, 51 rue Cognacq-Jay, F-51096 Reims Cedex, France
*
Author to whom correspondence should be addressed.
Received: 2 September 2014 / Revised: 19 September 2014 / Accepted: 24 September 2014 / Published: 30 September 2014
(This article belongs to the Special Issue Free Radicals and Radical Ions)
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Abstract

(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts. View Full-Text
Keywords: cyclization; heterocycle; oxindole; UV-light cyclization; heterocycle; oxindole; UV-light
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Gurry, M.; Allart-Simon, I.; McArdle, P.; Gérard, S.; Sapi, J.; Aldabbagh, F. Photochemical Aryl Radical Cyclizations to Give (E)-3-Ylideneoxindoles. Molecules 2014, 19, 15891-15899.

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