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Molecules 2013, 18(9), 10108-10121; doi:10.3390/molecules180910108
Review

Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis

1
, 2
, 3,*  and 3,*
Received: 16 July 2013; in revised form: 9 August 2013 / Accepted: 15 August 2013 / Published: 22 August 2013
(This article belongs to the Special Issue Palladium Catalysts)
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Abstract: The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric a-allylation of carbonyl compounds, a-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology.
Keywords: palladium; organocatalysis; asymmetric synthesis; dual activation; tandem reaction; allylation; fluorination; decarboxylative protonation palladium; organocatalysis; asymmetric synthesis; dual activation; tandem reaction; allylation; fluorination; decarboxylative protonation
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Fernández-Ibañez, M.Á.; Maciá, B.; Alonso, D.A.; Pastor, I.M. Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis. Molecules 2013, 18, 10108-10121.

AMA Style

Fernández-Ibañez MÁ, Maciá B, Alonso DA, Pastor IM. Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis. Molecules. 2013; 18(9):10108-10121.

Chicago/Turabian Style

Fernández-Ibañez, M. Á.; Maciá, Beatriz; Alonso, Diego A.; Pastor, Isidro M. 2013. "Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis." Molecules 18, no. 9: 10108-10121.


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