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Molecules 2013, 18(4), 4403-4418; doi:10.3390/molecules18044403
Article

Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides

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Received: 5 March 2013; in revised form: 21 March 2013 / Accepted: 21 March 2013 / Published: 15 April 2013
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Abstract: A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.
Keywords: C–H bond; oxidation; palladium C–H bond; oxidation; palladium
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Sit, W.-N.; Chan, C.-W.; Yu, W.-Y. Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides. Molecules 2013, 18, 4403-4418.

AMA Style

Sit W-N, Chan C-W, Yu W-Y. Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides. Molecules. 2013; 18(4):4403-4418.

Chicago/Turabian Style

Sit, Wing-Nga; Chan, Chun-Wo; Yu, Wing-Yiu. 2013. "Palladium(II)-Catalyzed othro-C–H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides." Molecules 18, no. 4: 4403-4418.


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