Synthesis and Binding Ability of Molecular Probes Based on a Phenanthroline Derivative: Theory and Experiment
Abstract
:1. Introduction
2. Results and Discussion
2.1. UV-Vis Titration
2.2. Fluorescence Response
2.3. Binding Constant
Anion a | Ks(1) | |
---|---|---|
H2PO4− | Absorption | (1.01 ± 0.08) × 105 |
Emission | (1.67 ± 0.22) × 105 | |
AcO− | Absorption | (3.43 ± 0.04) × 104 |
Emission | (2.89 ± 0.16) × 104 | |
F− | Absorption | (7.88 ± 0.11) × 104 |
Emission | (6.57 ± 0.35) × 104 |
2.4. 1H-NMR Titration
2.5. Theoretical Investigation
3. Experimental
General
4. Conclusions
Acknowledgments
Conflicts of Interest
References
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Shang, X.; Wang, Y.; Wei, X.; Fu, Z.; Zhang, J.; Xu, X. Synthesis and Binding Ability of Molecular Probes Based on a Phenanthroline Derivative: Theory and Experiment. Molecules 2013, 18, 14840-14848. https://doi.org/10.3390/molecules181214840
Shang X, Wang Y, Wei X, Fu Z, Zhang J, Xu X. Synthesis and Binding Ability of Molecular Probes Based on a Phenanthroline Derivative: Theory and Experiment. Molecules. 2013; 18(12):14840-14848. https://doi.org/10.3390/molecules181214840
Chicago/Turabian StyleShang, Xuefang, Yingling Wang, Xiaofang Wei, Zhiyuan Fu, Jinlian Zhang, and Xiufang Xu. 2013. "Synthesis and Binding Ability of Molecular Probes Based on a Phenanthroline Derivative: Theory and Experiment" Molecules 18, no. 12: 14840-14848. https://doi.org/10.3390/molecules181214840