Molecules 2013, 18(12), 14826-14839; doi:10.3390/molecules181214826
Article

Synthesis, Structures and Properties of Two Metal-Organic Coordination Polymers Derived from Manganese(ΙΙ), Thiabendazole and Polydentate Carboxylic Acids

1 College of Chemistry and Chemical Engineering Guangxi University for Nationalities, Nanning 530006, China 2 College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
* Author to whom correspondence should be addressed.
Received: 14 October 2013; in revised form: 22 November 2013 / Accepted: 26 November 2013 / Published: 2 December 2013
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Abstract: Two novel binuclear Mn(II) metal-organic coordination complexes [Mn2(TBZ)2(CDC)(C2O4)]n (1), {[Mn2(TBZ)2(BDC)0.5(BTC)(H2O)2]·ET}n (2), (where TBZ = thiabendazole, H2CDC = trans-1,4-cyclohexanedicarboxylic acid, H2C2O4 = oxalic acid, H3BTC = 1,3,5-benzenetricarboxylic acid, ET = ethanol, H2BDC = 1,4-benzenedicarboxylate) have been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, electrochemical analysis and single crystal X-ray diffraction. The X-ray structure analysis reveals that 1 is s two-dimensional layer and 2 is s one-dimensional chain. In complex 1, it reveals 2-D layers composed of multi-(bidentate) bridging ligands (CDC and C2O4), and in 2, the coordinated BTC ligands adopt a monodentate mode and with BDC ligands adopt alternately chelating Mn1 and Mn2 bridges into 1-D chains. The 3-D structures of the two complexes are stabilized by π-π stacking interactions and hydrogen bonds.
Keywords: thiabendazole; single-crystal structure; binuclear Mn(II) complex; hydrogen bonds

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MDPI and ACS Style

Liang, P.; Xia, W.-X.; Tian, W.-M.; Yin, X.-H. Synthesis, Structures and Properties of Two Metal-Organic Coordination Polymers Derived from Manganese(ΙΙ), Thiabendazole and Polydentate Carboxylic Acids. Molecules 2013, 18, 14826-14839.

AMA Style

Liang P, Xia W-X, Tian W-M, Yin X-H. Synthesis, Structures and Properties of Two Metal-Organic Coordination Polymers Derived from Manganese(ΙΙ), Thiabendazole and Polydentate Carboxylic Acids. Molecules. 2013; 18(12):14826-14839.

Chicago/Turabian Style

Liang, Peng; Xia, Wen-Xiu; Tian, Wei-Man; Yin, Xian-Hong. 2013. "Synthesis, Structures and Properties of Two Metal-Organic Coordination Polymers Derived from Manganese(ΙΙ), Thiabendazole and Polydentate Carboxylic Acids." Molecules 18, no. 12: 14826-14839.

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