Towards Recyclable NAD(P)H Regeneration Catalysts
AbstractRh(III)-TsDPEN, an immobilized analog of the well-known [Cp*Rh(bpy)(H2O)]2+ was evaluated as a heterogeneous, recyclable regeneration catalyst for reduced oxidoreductase cofactors [NAD(P)H]. Repeated use of this catalyst was established and the catalytic properties were initially investigated. Apparently, Rh(III)-TsDPEN is prone to severe diffusion limitations, necessitating further developments. Overall, a promising concept for chemoenzymatic redox catalysis is proposed, which may overcome some of the current limitations such as catalyst cost and incompatibility of Rh with some biocatalysts.
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de Torres, M.; Dimroth, J.; Arends, I.W.C.E.; Keilitz, J.; Hollmann, F. Towards Recyclable NAD(P)H Regeneration Catalysts. Molecules 2012, 17, 9835-9841.
de Torres M, Dimroth J, Arends IWCE, Keilitz J, Hollmann F. Towards Recyclable NAD(P)H Regeneration Catalysts. Molecules. 2012; 17(8):9835-9841.Chicago/Turabian Style
de Torres, Miriam; Dimroth, Jonas; Arends, Isabel W. C. E.; Keilitz, Juliane; Hollmann, Frank. 2012. "Towards Recyclable NAD(P)H Regeneration Catalysts." Molecules 17, no. 8: 9835-9841.