Molecules 2012, 17(7), 8533-8553; doi:10.3390/molecules17078533
Article

Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at Cd with Trimethylsilyl Azide

1,* email, 2email, 2email and 3email
Received: 13 June 2012; in revised form: 5 July 2012 / Accepted: 6 July 2012 / Published: 17 July 2012
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Abstract: This study presents a new reaction of cationic vinylidene complexes with Me3SiN3 (TMSN3), which yields N-coordinated nitrile complexes 3. Treatment of a ruthenium acetylide precursor containing indenyl and dppe ligands with a series of organic halides produced the corresponding vinylidene complexes 2 in good yield. Further reaction of 2 with TMSN3 at room temperature produced N-coordinated ruthenium nitrile complexes 3. Unlike the reaction of cyclopropenylruthenium complexes with TMSN3, which yielded different products depending on the substituent at Cγ, the vinylidene complexes containing unsaturated bonds at Cd yielded similar N-coordinated nitrile complexes. This transformation did not seemingly occur in the reaction of ruthenium vinylidene complexes containing Cp and PPh3 ligands with TMSN3. Deprotonation of these vinylidene complexes yielded cyclopropenyl or thermodynamic furylruthenium complexes, depending on the substitute at Cγ. Subsequent reactions of the cyclopropenyl or furylruthenium complexes with TMSN3 afforded different products.
Keywords: vinylidene; ruthenium; N-coordinated; cyclopropenyl; furyl; indenyl
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MDPI and ACS Style

Sung, H.-L.; Her, T.-M.; Su, W.-H.; Cheng, C.-P. Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at Cd with Trimethylsilyl Azide. Molecules 2012, 17, 8533-8553.

AMA Style

Sung H-L, Her T-M, Su W-H, Cheng C-P. Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at Cd with Trimethylsilyl Azide. Molecules. 2012; 17(7):8533-8553.

Chicago/Turabian Style

Sung, Hui-Ling; Her, Tze-Min; Su, Wen-Hsien; Cheng, Chin-Pao. 2012. "Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at Cd with Trimethylsilyl Azide." Molecules 17, no. 7: 8533-8553.


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