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Molecules 2012, 17(3), 2812-2822; https://doi.org/10.3390/molecules17032812

Efficient Synthesis of β-Enaminones and β-Enaminoesters Catalyzed by Gold (I)/Silver (I) under Solvent-Free Conditions

1
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
2
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
3
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
*
Author to whom correspondence should be addressed.
Received: 15 January 2012 / Revised: 16 February 2012 / Accepted: 17 February 2012 / Published: 6 March 2012
(This article belongs to the Section Organic Chemistry)
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Abstract

An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh3)AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good to excellent yields at room temperature.
Keywords: gold; solvent-free; amines; β-enaminones; β-enaminoesters gold; solvent-free; amines; β-enaminones; β-enaminoesters
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Zhang, M.; Abdukader, A.; Fu, Y.; Zhu, C. Efficient Synthesis of β-Enaminones and β-Enaminoesters Catalyzed by Gold (I)/Silver (I) under Solvent-Free Conditions. Molecules 2012, 17, 2812-2822.

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