SnCl2/TiCl3-Mediated Deoximation of Oximes in an Aqueous Solvent

doi:10.3390/molecules17032464

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Molecules 2012, 17(3), 2464-2473; doi:10.3390/molecules17032464

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SnCl₂/TiCl₃-Mediated Deoximation of Oximes in an Aqueous Solvent

Mei-Huey Lin* , Han-Jun Liu, Cheng-Yu Chang, Wei-Cheng Lin and Tsung-Hsun Chuang

Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan

* Author to whom correspondence should be addressed.

Received: 30 January 2012; in revised form: 23 February 2012 / Accepted: 27 February 2012 / Published: 1 March 2012

(This article belongs to the Section Organic Synthesis)

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Abstract: A simple procedure for SnCl₂/TiCl₃-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in good to excellent yields.

Keywords: deoximation; aqueous solvent; ketoxime; aldoxime; tin chloride; titanium trichloride

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Cite This Article

MDPI and ACS Style

Lin, M.-H.; Liu, H.-J.; Chang, C.-Y.; Lin, W.-C.; Chuang, T.-H. SnCl₂/TiCl₃-Mediated Deoximation of Oximes in an Aqueous Solvent. Molecules 2012, 17, 2464-2473.

AMA Style

Lin M-H, Liu H-J, Chang C-Y, Lin W-C, Chuang T-H. SnCl₂/TiCl₃-Mediated Deoximation of Oximes in an Aqueous Solvent. Molecules. 2012; 17(3):2464-2473.

Chicago/Turabian Style

Lin, Mei-Huey; Liu, Han-Jun; Chang, Cheng-Yu; Lin, Wei-Cheng; Chuang, Tsung-Hsun. 2012. "SnCl₂/TiCl₃-Mediated Deoximation of Oximes in an Aqueous Solvent." Molecules 17, no. 3: 2464-2473.

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