Next Article in Journal
Chemical Constituents from Stem Bark and Roots of Clausena anisata
Previous Article in Journal
Clerodendranoic Acid, a New Phenolic Acid from Clerodendranthus spicatus
Article Menu

Export Article

Open AccessArticle
Molecules 2012, 17(11), 13662-13672; https://doi.org/10.3390/molecules171113662

Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

1
Institute of Biotechnology and Pharmaceutical Research, National Health Research Institutes, Miaoli County 35053, Taiwan
2
Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan
3
Chinese Medicinal Research and Development Center, China Medical University Hospital, 2 Yude Road, Taichung 40447, Taiwan
*
Author to whom correspondence should be addressed.
Received: 21 September 2012 / Revised: 12 November 2012 / Accepted: 14 November 2012 / Published: 20 November 2012
(This article belongs to the Section Organic Chemistry)
Full-Text   |   PDF [232 KB, uploaded 18 June 2014]   |  

Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields. View Full-Text
Keywords: Beckmann rearrangement; phenyl dichlorophosphate; ketoximes; ambient temperature Beckmann rearrangement; phenyl dichlorophosphate; ketoximes; ambient temperature
Figures

Graphical abstract

This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
SciFeed

Share & Cite This Article

MDPI and ACS Style

Kuo, C.-W.; Hsieh, M.-T.; Gao, S.; Shao, Y.-M.; Yao, C.-F.; Shia, K.-S. Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature. Molecules 2012, 17, 13662-13672.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top