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Molecules 2012, 17(11), 13662-13672; doi:10.3390/molecules171113662

Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

1
Institute of Biotechnology and Pharmaceutical Research, National Health Research Institutes, Miaoli County 35053, Taiwan
2
Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan
3
Chinese Medicinal Research and Development Center, China Medical University Hospital, 2 Yude Road, Taichung 40447, Taiwan
*
Author to whom correspondence should be addressed.
Received: 21 September 2012 / Revised: 12 November 2012 / Accepted: 14 November 2012 / Published: 20 November 2012
(This article belongs to the Section Organic Synthesis)
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Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
Keywords: Beckmann rearrangement; phenyl dichlorophosphate; ketoximes; ambient temperature Beckmann rearrangement; phenyl dichlorophosphate; ketoximes; ambient temperature
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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Kuo, C.-W.; Hsieh, M.-T.; Gao, S.; Shao, Y.-M.; Yao, C.-F.; Shia, K.-S. Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature. Molecules 2012, 17, 13662-13672.

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