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Molecules 2010, 15(5), 3441-3461; doi:10.3390/molecules15053441

Carbon-Carbon Cross Coupling Reactions in Ionic Liquids Catalysed by Palladium Metal Nanoparticles

1
Laboratory of Molecular Catalysis, Universidade Federal do Rio Grande do Sul, Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre/RS, Brazil
2
Institute of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany
*
Author to whom correspondence should be addressed.
Received: 16 April 2010 / Revised: 6 May 2010 / Accepted: 11 May 2010 / Published: 12 May 2010
(This article belongs to the Special Issue Nano-catalysts and Nano-technologies for Green Organic Synthesis)
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Abstract

A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media and the use of palladium nanoparticles as reservoir for the catalytically active palladium species.
Keywords: palladium; nanoparticles; ionic liquids; cross-coupling; Heck; Suzuki; Stille; Sonogashira; Ullmann palladium; nanoparticles; ionic liquids; cross-coupling; Heck; Suzuki; Stille; Sonogashira; Ullmann
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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Prechtl, M.H.G.; Scholten, J.D.; Dupont, J. Carbon-Carbon Cross Coupling Reactions in Ionic Liquids Catalysed by Palladium Metal Nanoparticles. Molecules 2010, 15, 3441-3461.

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