Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore

doi:10.3390/molecules14062111

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Molecules 2009, 14(6), 2111-2117; doi:10.3390/molecules14062111

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Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore

Zhen-Ting Du^1,* , Ru Liu¹, Jun-Ru Wang¹ and An-Pai Li^2,*

¹ College of Sciences, Northwest A&F University, Yangling, Shaanxi 712100, China ² Synthetics Technologica Pte Ltd, 3 Phillip Street, #18-00 Commerce Point, 048693, Singapore

* Authors to whom correspondence should be addressed.

Received: 24 April 2009; in revised form: 1 June 2009 / Accepted: 3 June 2009 / Published: 10 June 2009

(This article belongs to the Special Issue Macromolecules: Chemistry, Medicinal and Functional Materials)

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Abstract: (E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W.

Keywords: chromophore; energy transfer; synthesis; terphenyldivinyl

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MDPI and ACS Style

Du, Z.-T.; Liu, R.; Wang, J.-R.; Li, A.-P. Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore. Molecules 2009, 14, 2111-2117.

AMA Style

Du Z-T, Liu R, Wang J-R, Li A-P. Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore. Molecules. 2009; 14(6):2111-2117.

Chicago/Turabian Style

Du, Zhen-Ting; Liu, Ru; Wang, Jun-Ru; Li, An-Pai. 2009. "Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore." Molecules 14, no. 6: 2111-2117.

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