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Molecules 2009, 14(6), 2111-2117; doi:10.3390/molecules14062111

Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore

1,* , 1
1 College of Sciences, Northwest A&F University, Yangling, Shaanxi 712100, China 2 Synthetics Technologica Pte Ltd, 3 Phillip Street, #18-00 Commerce Point, 048693, Singapore
* Authors to whom correspondence should be addressed.
Received: 24 April 2009 / Revised: 1 June 2009 / Accepted: 3 June 2009 / Published: 10 June 2009
(This article belongs to the Special Issue Macromolecules: Chemistry, Medicinal and Functional Materials)
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(E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W.
Keywords: chromophore; energy transfer; synthesis; terphenyldivinyl chromophore; energy transfer; synthesis; terphenyldivinyl
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Du, Z.-T.; Liu, R.; Wang, J.-R.; Li, A.-P. Synthesis of a Diamino Substituted Terphenyldivinyl Chromophore. Molecules 2009, 14, 2111-2117.

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