Complexes of 3dn Metal Ions with Thiosemicarbazones: Synthesis and Antimicrobial Activity
AbstractThe chelating behavior of the thiosemicarbazone derivatives of 2-hydroxy-8-R-tricyclo[184.108.40.206.2,7]tridecane-13-one (where R = H, CH3, C6H5) towards Co(II), Ni(II) and Cu(II) has been investigated by elemental analysis, molar conductivity measurements, UV-VIS, IR, ESR spectroscopy and thermal studies. It was deduced from the experiments performed that the ligands coordinate to metal ions in different ways – neutral bidentate or mononegative bidentate – depending on the nature of R. Also, if metal acetates are used instead of metal chlorides, the ligands coordinate in a mononegative bidentate fashion, regardless of the nature of R or the thiosemicarbazone type ligand. The antimicrobial activity of the ligands and of the complexes towards samples of Acinetobacter boumanii, Klebsiella pneumoniae, Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa was determined. View Full-Text
- Supplementary File 1:
DOC-Document (DOC, 226 KB)
Scifeed alert for new publicationsNever miss any articles matching your research from any publisher
- Get alerts for new papers matching your research
- Find out the new papers from selected authors
- Updated daily for 49'000+ journals and 6000+ publishers
- Define your Scifeed now
Rosu, T.; Gulea, A.; Nicolae, A.; Georgescu, R. Complexes of 3dn Metal Ions with Thiosemicarbazones: Synthesis and Antimicrobial Activity. Molecules 2007, 12, 782-796.
Rosu T, Gulea A, Nicolae A, Georgescu R. Complexes of 3dn Metal Ions with Thiosemicarbazones: Synthesis and Antimicrobial Activity. Molecules. 2007; 12(4):782-796.Chicago/Turabian Style
Rosu, Tudor; Gulea, Aurelian; Nicolae, Anca; Georgescu, Rodica. 2007. "Complexes of 3dn Metal Ions with Thiosemicarbazones: Synthesis and Antimicrobial Activity." Molecules 12, no. 4: 782-796.