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Molecules 2006, 11(2), 163-168; doi:10.3390/11020163

Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by π−π Stacking Interactions

Department of Chemistry and Biochemistry, San Diego State University, 5500 Campanile Drive, San Diego, CA, 92182, USA
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Received: 1 September 2005 / Revised: 14 February 2006 / Accepted: 14 February 2006 / Published: 14 February 2006
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Abstract

The synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) å, b=7.153(3) å,c=14.193(6) å, α=90.00, β=90.00, γ=90.00, V=3220(2) å3, Z=9. π−π stacking contactsinvolving interactions between the π-donor benzene and the π-acceptor pyridine systemsreinforce and direct the self-assembly of the structural motifs in the solid state.
Keywords: Sulfonate; Water-soluble Ligand; π−π Stacking; Michael-type Addition. Sulfonate; Water-soluble Ligand; π−π Stacking; Michael-type Addition.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Zhang, Y.; Liang, H.-C. Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by π−π Stacking Interactions. Molecules 2006, 11, 163-168.

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