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Molecules 2005, 10(8), 843-858; doi:10.3390/10080843
Article

Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides

*  and
Ecole Normale Supérieure, Département de Chimie, France
* Author to whom correspondence should be addressed.
Received: 8 October 2004 / Revised: 4 November 2004 / Accepted: 10 November 2004 / Published: 31 August 2005
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Abstract

Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
Keywords: Carbohydrates; C-glycosides; carbocycles; rearrangements Carbohydrates; C-glycosides; carbocycles; rearrangements
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Sollogoub, M.; Sinay, P. Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides. Molecules 2005, 10, 843-858.

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