Next Article in Journal
Epoxidation and Bis-hydroxylation of C-Phenyl-∆2,3-glycopyranosides
Previous Article in Journal
Pyrimidine Acyclo-C-Nucleosides by Ring Transformations of 2-Formyl-L-arabinal
Molecules 2005, 10(8), 843-858; doi:10.3390/10080843

Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides

*  and
Ecole Normale Supérieure, Département de Chimie, France
* Author to whom correspondence should be addressed.
Received: 8 October 2004 / Revised: 4 November 2004 / Accepted: 10 November 2004 / Published: 31 August 2005
Download PDF [179 KB, uploaded 18 June 2014]


Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
Keywords: Carbohydrates; C-glycosides; carbocycles; rearrangements Carbohydrates; C-glycosides; carbocycles; rearrangements
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
MDPI and ACS Style

Sollogoub, M.; Sinay, P. Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides. Molecules 2005, 10, 843-858.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here


Cited By

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert