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Molecules 2005, 10(3), 516-520; doi:10.3390/10030516

A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, Banacha 1, PL 02-097 Warsaw, Poland
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Received: 10 November 2004 / Accepted: 10 March 2005 / Published: 13 May 2005
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Abstract

Benzene, halobenzenes and some deactivated arenes readily reacted inanhydrous NaIO4/AcOH/Ac2O/concd. H2SO4 mixtures to afford, after quenching withexcess aqueous Na2SO3 solution (a reducing agent), purified iodinated products in 27-88% yields. This novel method of aromatic iodination is simple, fairly effective andenvironmentally safe.
Keywords: Arenes; iodoarenes; aromatic iodination; sodium periodate; periodyl organic intermediates. Arenes; iodoarenes; aromatic iodination; sodium periodate; periodyl organic intermediates.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Luliński, P.; Sosnowski, M.; Skulski, L. A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent. Molecules 2005, 10, 516-520.

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