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Molecules 2005, 10(1), 195-200; doi:10.3390/10010195
Article

Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane

, ,  and *
Faculty of Pharmaceutical Sciences, University of Tokushima, Japan
* Author to whom correspondence should be addressed.
Received: 11 May 2004 / Revised: 24 November 2004 / Accepted: 25 November 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
Keywords: Radical; iodane; ether; vinyl sulfone; maleate Radical; iodane; ether; vinyl sulfone; maleate
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Sueda, T.; Takeuchi, Y.; Suefuji, T.; Ochiai, M. Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane. Molecules 2005, 10, 195-200.

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