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Molecules 2005, 10(1), 195-200; doi:10.3390/10010195
Article

Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane

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Received: 11 May 2004; in revised form: 24 November 2004 / Accepted: 25 November 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract: Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
Keywords: Radical; iodane; ether; vinyl sulfone; maleate Radical; iodane; ether; vinyl sulfone; maleate
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Sueda, T.; Takeuchi, Y.; Suefuji, T.; Ochiai, M. Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane. Molecules 2005, 10, 195-200.

AMA Style

Sueda T, Takeuchi Y, Suefuji T, Ochiai M. Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane. Molecules. 2005; 10(1):195-200.

Chicago/Turabian Style

Sueda, T.; Takeuchi, Y.; Suefuji, T.; Ochiai, M. 2005. "Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane." Molecules 10, no. 1: 195-200.



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