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Molecules 2005, 10(1), 201-216; doi:10.3390/10010201
Article

Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation

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Received: 28 May 2004; Accepted: 25 July 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
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Abstract: Treatment of 2-methylphenols with chloro(diphenyl)-λ3-iodane led to theirregioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via aproposed ligand coupling reaction. In the same vein of investigation, treatment of2-methylanilines with the λ5-iodane 2-iodoxybenzoic acid IBX reagent led to theirregioselective dearomatization into previously undescribed ortho-quinol imines.
Keywords: Iodanes; phenols; anilines; dearomatization; cyclohexadienones; orthoquinol imines Iodanes; phenols; anilines; dearomatization; cyclohexadienones; orthoquinol imines
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Quideau, S.; Pouységu, L.; Ozanne, A.; Gagnepain, J. Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation. Molecules 2005, 10, 201-216.

AMA Style

Quideau S, Pouységu L, Ozanne A, Gagnepain J. Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation. Molecules. 2005; 10(1):201-216.

Chicago/Turabian Style

Quideau, S.; Pouységu, L.; Ozanne, A.; Gagnepain, J. 2005. "Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation." Molecules 10, no. 1: 201-216.


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