Molecules 2005, 10(1), 201-216; doi:10.3390/10010201
Article

Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation

Institut Européen de Chimie et Biologie and Laboratoire de Chimie des Substances Végétales, Centre de Recherche en Chimie Moléculaire, Université Bordeaux 1, France
* Author to whom correspondence should be addressed.
Received: 28 May 2004; Accepted: 25 July 2004 / Published: 31 January 2005
(This article belongs to the Special Issue Hypervalent Iodine)
PDF Full-text Download PDF Full-Text [291 KB, uploaded 20 June 2008 16:49 CEST]
Abstract: Treatment of 2-methylphenols with chloro(diphenyl)-λ3-iodane led to theirregioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via aproposed ligand coupling reaction. In the same vein of investigation, treatment of2-methylanilines with the λ5-iodane 2-iodoxybenzoic acid IBX reagent led to theirregioselective dearomatization into previously undescribed ortho-quinol imines.
Keywords: Iodanes; phenols; anilines; dearomatization; cyclohexadienones; orthoquinol imines

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Quideau, S.; Pouységu, L.; Ozanne, A.; Gagnepain, J. Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation. Molecules 2005, 10, 201-216.

AMA Style

Quideau S, Pouységu L, Ozanne A, Gagnepain J. Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation. Molecules. 2005; 10(1):201-216.

Chicago/Turabian Style

Quideau, S.; Pouységu, L.; Ozanne, A.; Gagnepain, J. 2005. "Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation." Molecules 10, no. 1: 201-216.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert