Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products

doi:10.3390/10010190

This article is

freely available
re-usable

Molecules 2005, 10(1), 190-194; doi:10.3390/10010190

Article

Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted ¹H- and ¹³C-NMR Spectra of the Products

Agnieszka Zielinska and Lech Skulski*

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, 1 Banacha Street, PL 02-097 Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 30 April 2004; in revised form: 12 January 2005 / Accepted: 13 January 2005 / Published: 31 January 2005

(This article belongs to the Special Issue Hypervalent Iodine)

Download PDF Full-Text [154 KB, uploaded 20 June 2008 16:49 CEST]

Abstract: An easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fullyinterpreted ¹H- and ¹³C-NMR spectra of the ArI(OAc)2 products are reported.

Keywords: (Diacetoxyiodo)arenes; iodoarenes; urea-hydrogen peroxide adduct as oxidant; 1H- and 13C-NMR spectra

Article Statistics

Click here to load and display the download statistics.

Cite This Article

MDPI and ACS Style

Zielinska, A.; Skulski, L. Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted ¹H- and ¹³C-NMR Spectra of the Products. Molecules 2005, 10, 190-194.

AMA Style

Zielinska A, Skulski L. Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted ¹H- and ¹³C-NMR Spectra of the Products. Molecules. 2005; 10(1):190-194.

Chicago/Turabian Style

Zielinska, Agnieszka; Skulski, Lech. 2005. "Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted ¹H- and ¹³C-NMR Spectra of the Products." Molecules 10, no. 1: 190-194.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert