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Entropy 2014, 16(11), 5954-5975; doi:10.3390/e16115954

Self-Organization at Aqueous Colloid-Membrane Interfaces and an Optical Method to Measure the Kinetics of Exclusion Zone Formation

and
†,*
Institute for Frontier Science, 6114 LaSalle Ave #605, Oakland, CA 94611, USA
These authors contributed equally to this work.
*
Author to whom correspondence should be addressed.
Received: 14 July 2014 / Revised: 9 November 2014 / Accepted: 11 November 2014 / Published: 17 November 2014
(This article belongs to the Special Issue Entropy and EZ-Water)

Abstract

Exclusion zone (EZ) formation at water-membrane interfaces was studied via bright- and dark-field microscopy. Various aqueous colloids including suspensions of charged microspheres, silicon dioxide particles, and raw whole milk were studied with Nafion® hydrophilic membranes. Interfacial formations observed included EZs and more complex patterns including striations, double layers, banding, dendritic aggregates of particles, and double-stranded structures resembling Birkeland current filaments in cold plasmas. A complex three-dimensional dynamic structure and continuous flow patterns persist in and around EZs, maintaining movement of the colloidal particles even after EZs are fully formed, for which a schematic is proposed. Since radiant energy is critical for EZ formation, we hypothesize that these interfacial phenomena are non-equilibrium dissipative structures that self-organize and self-maintain due to ongoing dynamic processes that may involve hydrodynamic interactions. Another experimental approach undertaken involved the construction of a microscope flow cell to measure the kinetics of EZ formation using sequential microphotography analyzed with macro-programmed ImageJ software to investigate effects of different types of conditioned water. No significant difference was found between spring water and the same water treated by a magnetic vortexer. A significant difference was found for municipal tap water compared to electrolyzed alkaline tap water from the same source. View Full-Text
Keywords: interfacial water; exclusion zone; aqueous colloid; self-organization; non-equilibrium; dissipative structure interfacial water; exclusion zone; aqueous colloid; self-organization; non-equilibrium; dissipative structure
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Jabs, H.; Rubik, B. Self-Organization at Aqueous Colloid-Membrane Interfaces and an Optical Method to Measure the Kinetics of Exclusion Zone Formation. Entropy 2014, 16, 5954-5975.

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