New Developments in Boron Chemistry: From Oxidoborates to Hydrido(hetero)borane Derivatives – in Celebration of Professor John D. Kennedy’s 80th Birthday

doi:10.3390/books978-3-7258-0665-2

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New Developments in Boron Chemistry: From Oxidoborates to Hydrido(hetero)borane Derivatives – in Celebration of Professor John D. Kennedy’s 80th Birthday

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April 2024

478 pages

ISBN978-3-7258-0666-9 (Hardback)
ISBN978-3-7258-0665-2 (PDF)

https://doi.org/10.3390/books978-3-7258-0665-2

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This book is a reprint of the Special Issue New Developments in Boron Chemistry: From Oxidoborates to Hydrido(hetero)borane Derivatives – in Celebration of Professor John D. Kennedy’s 80th Birthday that was published in

Chemistry & Materials Science

Medicine & Pharmacology

Summary

This Special Issue is dedicated to all aspects of boron chemistry, including all fields of inorganic boron chemistry from oxidoborates to hydrido(hetero)borane derivatives (including boranes, carboranes, metallaboranes, and metallacarboranes), transition metal complexes of boron-containing ligands, organic and bio-organic boron chemistry (including boron-based Lewis acids, boronic acids, benzoxaboroles, aminoboranes, and the application of boron reagents in organic synthesis), boron in materials (including polymers, dendrimers, ionic liquids, liquid crystals, hydrogen storage, and catalysis), and boron in medicine (including boron neutron capture of cancer, carborane pharmacophores, boron-containing drugs, and boronic acid-based sugar sensors).

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Keywords

reduction; ammonia-borane; nitrile; primary amines; titanium tetrachloride; catalysis; organoboron; non-fullerene acceptor-based organic solar cells; density functional theory; charge transport; charge transfer; adduct; amine borane; boranes; boron chemistry; dihydrogen bonds; monocarba-hydridoborate; polymorphism; crystal structure; anion dynamics; polyhedral boranes; sulfur; selenium; cobalt; density functional there; dodecaborate(2-); dodecahydrido-closo-dodecaborate(2-); Pd catalysis; halogen exchange; click reaction; borate; guanidinium salts; H-bonding; oxidoborate; pentaborate(1-); R₂²(8) motifs; tetrahydroxidohexaoxidopentaborate(1-) salts; XRD; amine-borane; dehydrogenative borylation; lithium aminoborohydrides; alkynylborane-amines; 1,1-dibromoolefin; 3-amino-1,2-dicarba-closo-dodecaborane; RGD peptide; linker fragment; protecting groups; carboranes; N-heterocyclic carbenes; cations; DFT; reaction pathways; boron; carborane; p-carborane; lithiation; carboranylamidinate; metallacarboranes; cobalt bis(1,2-dicarbollide); oligofunctionalization; alkylation; stereochemistry; triarylborane; fluorescent probe; circular dichroism; DNA recognition; RNA recognition; aluminoborates; oxoboron cluster; 3D porous layers; solvothermal syntheses; carboranes; metallabis(dicarbollide); BNCT; proton therapy; PBFR; COSAN; FESAN; PET; SPECT; antimicrobial; luminescence; bioimaging; photodinamic therapy (PDT); anti-B₁₈H₂₂; luminescence; fluorescence; cluster boron hydrides; chlorination; halogenation; substitution; excited-state lifetime; quantum yield; carboranes; inflammation; cyclooxygenases; lipoxygenases; cancer; scorpionate; copper; borohydride; ligand; nitrogen; coordination; borate; edge-sharing; fundamental building blocks; structural chemistry; boron; boronic acid ester; Lewis acid–base adduct; self-assembly; boronic acid; dative N→B bonding; host–guest complex; π–π stacking; aromatic hydrocarbons; boron; diborane(4); boryl complex; PBP pincer ligand; decaborane; history; properties; derivatives; boranes; metallaboranes; metal hydrides; fluxionality; solid-state structure; acridine; cobalt bis(dicarbollide); synthesis; DNA-interaction; antiproliferative activity; borane; carborane; dicarbollide; cobalt bis(dicarbollide); lithiation; metalation