Next Article in Journal / Special Issue
A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)
Previous Article in Journal / Special Issue
Structure and Magnetic Properties of the Spin Crossover Linear Trinuclear Complex [Fe3(furtrz)6(ptol)2(MeOH)4]·4(ptol)·4(MeOH) (furtrz: furanylidene-4H-1,2,4-triazol-4-amine ptol: p-tolylsulfonate)
Article Menu

Export Article

Open AccessArticle
Magnetochemistry 2016, 2(1), 8; doi:10.3390/magnetochemistry2010008

Spin-Crossover Behavior of Hofmann-Type-Like Complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O Depending on Guest Species

1
Department of Basic Science, Graduate School of Arts and Sciences, the University of Tokyo, 3-8-1, Komaba, Meguro-ku, Tokyo 153-8902, Japan
2
Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan
3
Research Centre for Materials with Integrated Properties, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan
These authors contributed equally to this work.
*
Author to whom correspondence should be addressed.
Academic Editors: Guillem Aromí and José Antonio Real
Received: 7 January 2016 / Revised: 26 January 2016 / Accepted: 1 February 2016 / Published: 16 February 2016
(This article belongs to the Special Issue Spin Crossover (SCO) Research)
View Full-Text   |   Download PDF [960 KB, uploaded 16 February 2016]   |  

Abstract

A newly prepared metal complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O, which was estimated to have a structure similar to the Hofmann-type clathrate host, changed its color from orange to deep orange and yellow on exposure to ethanol and acetone vapor, respectively, and the respective samples showed thermally induced two-step and one-step spin transitions. View Full-Text
Keywords: spin-crossover; vapochromism; guest inclusion; isotope effect spin-crossover; vapochromism; guest inclusion; isotope effect
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Hosoya, K.; Nishikiori, S.-I.; Takahashi, M.; Kitazawa, T. Spin-Crossover Behavior of Hofmann-Type-Like Complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O Depending on Guest Species. Magnetochemistry 2016, 2, 8.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Magnetochemistry EISSN 2312-7481 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top