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Magnetochemistry 2016, 2(1), 9; doi:10.3390/magnetochemistry2010009

A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

School of Physical Sciences, University of Kent, Canterbury, Kent CT2 7NH, UK
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
Author to whom correspondence should be addressed.
Academic Editor: Guillem Aromí
Received: 11 January 2016 / Revised: 31 January 2016 / Accepted: 2 February 2016 / Published: 17 February 2016
(This article belongs to the Special Issue Spin Crossover (SCO) Research)
View Full-Text   |   Download PDF [3209 KB, uploaded 17 February 2016]   |  


A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition. View Full-Text
Keywords: spin-crossover; molecular materials; high pressure; order-disorder phenomena spin-crossover; molecular materials; high pressure; order-disorder phenomena

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Shepherd, H.J.; Tonge, G.; Hatcher, L.E.; Bryant, M.J.; Knichal, J.V.; Raithby, P.R.; Halcrow, M.A.; Kulmaczewski, R.; Gagnon, K.J.; Teat, S.J. A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry 2016, 2, 9.

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