Next Article in Journal / Special Issue
Rational Control of Spin-Crossover Particle Sizes: From Nano- to Micro-Rods of [Fe(Htrz)2(trz)](BF4)
Previous Article in Journal / Special Issue
Spin-Crossover Behavior of Hofmann-Type-Like Complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O Depending on Guest Species
Article Menu

Export Article

Open AccessArticle
Magnetochemistry 2016, 2(1), 9; doi:10.3390/magnetochemistry2010009

A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

1
School of Physical Sciences, University of Kent, Canterbury, Kent CT2 7NH, UK
2
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
3
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
4
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
*
Author to whom correspondence should be addressed.
Academic Editor: Guillem Aromí
Received: 11 January 2016 / Revised: 31 January 2016 / Accepted: 2 February 2016 / Published: 17 February 2016
(This article belongs to the Special Issue Spin Crossover (SCO) Research)
View Full-Text   |   Download PDF [3209 KB, uploaded 17 February 2016]   |  

Abstract

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition. View Full-Text
Keywords: spin-crossover; molecular materials; high pressure; order-disorder phenomena spin-crossover; molecular materials; high pressure; order-disorder phenomena
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Shepherd, H.J.; Tonge, G.; Hatcher, L.E.; Bryant, M.J.; Knichal, J.V.; Raithby, P.R.; Halcrow, M.A.; Kulmaczewski, R.; Gagnon, K.J.; Teat, S.J. A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry 2016, 2, 9.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Magnetochemistry EISSN 2312-7481 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top