An Alternative Use of Olive Pomace as a Wide-Ranging Bioremediation Strategy to Adsorb and Recover Disperse Orange and Disperse Red Industrial Dyes from Wastewater
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Preparation of the Biosorbent
2.3. Experimental Procedures
2.4. UV-Visible and Fourier Transform Infra-Red Spectroscopy in Total Attenuated Reflectance (FTIR-ATR) Measurements
2.5. X-Ray Photoelectron Spectroscopy (XPS) Analysis
2.6. Scanning Electron Microscopy (SEM)
2.7. Thermogravimetry Analysis (TGA)
2.8. Desorption Studies
3. Results and Discussion
3.1. Cycles of Consecutive Adsorption of Disperse Orange and Red Dyes
3.2. Desorption Studies
3.3. Thermogravimetric Analyses (TGA)
3.4. FTIR-ATR Spectroscopic Measurements
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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OP or OPP | OP + DO | OP + DR | ||||||
---|---|---|---|---|---|---|---|---|
g | % | OP Time (min) | % | OPP Time (min) | % | OP Time (min) | % | OPP Time (min) |
0.25 | 85 | 180 | 98 | 40 | 99 | 180 | 98 | 30 |
0.50 | 99 | 180 | 97 | 30 | 97 | 120 | 97 | 20 |
1.00 | 97 | 60 | 99 | 10 | 98 | 30 | 99 | 10 |
3.00 | 98 | 30 | 97 | 10 | 97 | 10 | 97 | 10 |
Cycles | OPP + DO | OPP + DR | ||
---|---|---|---|---|
Efficiency (%) | Time (min) | Efficiency (%) | Time (min) | |
1 | 97 | 10 | 97 | 10 |
2 | 98 | 10 | 98 | 10 |
3 | 96 | 20 | 95 | 20 |
4 | 95 | 20 | 95 | 20 |
5 | 95 | 20 | 96 | 20 |
Cycles | Adsorption/Desorption | OPP + DO | OPP + DR | ||
---|---|---|---|---|---|
Efficiency (%) | Time (min) | Efficiency (%) | Time (min) | ||
1 | Adsorption | 99 | 10 | 97 | 10 |
Desorption | 98 | 120 | 86 | 120 | |
2 | Adsorption | 98 | 20 | 98 | 30 |
Desorption | 97 | 120 | 85 | 120 | |
3 | Adsorption | 97 | 30 | 96 | 30 |
Desorption | 98 | 120 | 84 | 120 | |
4 | Adsorption | 96 | 40 | 99 | 60 |
Desorption | 97 | 120 | 98 | 120 | |
5 | Adsorption | 97 | 30 | 96 | 60 |
Desorption | 98 | 120 | 75 | 120 |
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Rizzi, V.; D’Agostino, F.; Gubitosa, J.; Fini, P.; Petrella, A.; Agostiano, A.; Semeraro, P.; Cosma, P. An Alternative Use of Olive Pomace as a Wide-Ranging Bioremediation Strategy to Adsorb and Recover Disperse Orange and Disperse Red Industrial Dyes from Wastewater. Separations 2017, 4, 29. https://doi.org/10.3390/separations4040029
Rizzi V, D’Agostino F, Gubitosa J, Fini P, Petrella A, Agostiano A, Semeraro P, Cosma P. An Alternative Use of Olive Pomace as a Wide-Ranging Bioremediation Strategy to Adsorb and Recover Disperse Orange and Disperse Red Industrial Dyes from Wastewater. Separations. 2017; 4(4):29. https://doi.org/10.3390/separations4040029
Chicago/Turabian StyleRizzi, Vito, Francesco D’Agostino, Jennifer Gubitosa, Paola Fini, Andrea Petrella, Angela Agostiano, Paola Semeraro, and Pinalysa Cosma. 2017. "An Alternative Use of Olive Pomace as a Wide-Ranging Bioremediation Strategy to Adsorb and Recover Disperse Orange and Disperse Red Industrial Dyes from Wastewater" Separations 4, no. 4: 29. https://doi.org/10.3390/separations4040029