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Editorial

Advances in Supported Nanoparticle Catalysts

by
Sónia Alexandra Correia Carabineiro
LAQV-REQUIMTE, Department of Chemistry, NOVA School of Science and Technology, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal
Processes 2024, 12(2), 365; https://doi.org/10.3390/pr12020365
Submission received: 20 January 2024 / Accepted: 6 February 2024 / Published: 9 February 2024
(This article belongs to the Special Issue Advances in Supported Nanoparticle Catalysts)
In catalysis, the design and application of supported nanoparticle catalysts is a cornerstone for addressing contemporary challenges in environmental remediation, sustainable synthesis, and analytical methodologies [1,2,3,4,5,6]. This Special Issue of Processes brings together a collection of research papers that exemplify the forefront of innovation in developing and utilizing supported nanoparticle catalysts.
One of the contributions in this issue focuses on the highly efficient removal of anionic dyes from water, achieved through cationic polymer brush-functionalized magnetic mesoporous silica nanoparticles (contribution 1). This study underscores the efficiency of supported nanoparticles and highlights their potential in addressing water pollution challenges.
In pursuing sustainable chemical transformations, the synthesis of palladium and copper nanoparticles supported on TiO2 for the solvent-free aerobic oxidation of benzyl alcohol showcases the catalytic efficiency of supported metal nanoparticles in environmentally benign processes (contribution 2).
A distinctive approach to material design is explored in the study on fabricating high-yield superhydrophobic carbon nanomaterials using a cobalt/iron co-catalyst impregnated on powdered activated carbon (contribution 3). This work advances the superhydrophobic materials field and demonstrates the synergistic effects of co-catalysts in nanoparticle synthesis.
Nanotechnology and electrochemiluminescence are joined together in the research focusing on polymer nanoparticle enhancement and particle structure stabilization by doping anionic polyelectrolyte and cationic polymer containing tertiary amine groups (contribution 4). The findings have significant implications for highly sensitive immunoanalysis applications.
The main focus is photocatalysis, with research into the effects of gold and ruthenium on the band gap in TiO2 support (contribution 5). Understanding the intricacies of these supported nanoparticle systems is crucial for optimizing photocatalytic processes for environmental and energy applications.
Glycerol oxidation over supported gold catalysts is explored in another significant contribution, unveiling the combined effects of gold particle size and the basicity of the support (contribution 6). This work contributes valuable insights into the design principles of supported gold catalysts for diverse catalytic applications.
The biogenic synthesis of magnetic nanoparticles of Fe3O4 using Cnicus benedictus extract opens up new possibilities for photocatalytic organic dye degradation and antibacterial behavior (contribution 7). This eco-friendly nanoparticle synthesis approach further expands the sustainable catalyst fabrication toolbox.
The physicochemical properties and CO oxidation performance of nanostructured CeO2/TiO2 oxides are systematically investigated, shedding light on the influence of the preparation method (contribution 8). Such insights are crucial for tailoring nanostructured catalysts for enhanced performance in various catalytic reactions.
Exploring the influence of electrostatic interactions during the resorcinol—formaldehyde polymerization on the characteristics of Mo-doped carbon gels provides an understanding of the factors influencing the properties of supported nanoparticle catalysts (contribution 9).
Finally, this Special Issue also deals with a review of hydrogenation reactions using supported palladium nanocatalysts (contribution 10), emphasizing the significance of supported metal nanoparticles in catalyzing crucial industrial processes.
As the guest editor for this Special Issue, I am thankful to all the contributing authors and the dedicated staff members at MDPI for their great editorial support. I am confident that readers will discover the papers featured in this Special Issue to be important examples of the application of supported nanoparticles in catalytic processes.

Funding

S.A.C.C. is grateful to Fundação para a Ciência e a Tecnologia (FCT), Portugal for Scientific Employment Stimulus-Institutional Call (DOI 10.54499/CEECINST/00102/2018/CP1567/CT0026) and the Associate Laboratory for Green Chemistry- LAQV financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/5006/2020).

Acknowledgments

S.A.C.C. is grateful to Fundação para a Ciência e a Tecnologia (FCT), Portugal for Scientific Employment Stimulus-Institutional Call (DOI 10.54499/CEECINST/00102/2018/CP1567/CT0026) and the Associate Laboratory for Green Chemistry- LAQV financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/5006/2020).

Conflicts of Interest

I declare no conflicts of interest.

List of Contributions

  • Beagan, A.; Alshammari, R.; Alotaibi, L.; Albarrak, H.; Alotaibi, K.; Alswieleh, A. High-Efficient Anionic Dyes Removal from Water by Cationic Polymer Brush Functionalized Magnetic Mesoporous Silica Nanoparticles. Processes 2022, 10, 1565.
  • Alshammari, H.M. Synthesis of Palladium and Copper Nanoparticles Supported on TiO2 for Oxidation Solvent-Free Aerobic Oxidation of Benzyl Alcohol. Processes 2021, 9, 1590.
  • Betar, B.O.; Alsaadi, M.A.; Chowdhury, Z.Z.; Aroua, M.K.; Mjalli, F.S.; Niazi, M.M. High Yield Superhydrophobic Carbon Nanomaterials Using Cobalt/Iron Co-Catalyst Impregnated on Powder Activated Carbon. Processes 2021, 9, 134.
  • Ul Ain, N.; Wang, T.-Y.; Wu, X.-N.; Wei, T.-H.; Zhang, J.-S.; Xie, H.-P. Electrochemiluminescence Enhancement and Particle Structure Stabilization of Polymer Nanoparticle by Doping Anionic Polyelectrolyte and Cationic Polymer Containing Tertiary Amine Groups and Its Highly Sensitive Immunoanalysis. Processes 2020, 8, 1054.
  • Fonseca-Cervantes, O.R.; Pérez-Larios, A.; Romero Arellano, V.H.; Sulbaran-Rangel, B.; Guzmán González, C.A. Effects in Band Gap for Photocatalysis in TiO2 Support by Adding Gold and Ruthenium. Processes 2020, 8, 1032.
  • Pakrieva, E.; Kolobova, E.; German, D.; Stucchi, M.; Villa, A.; Prati, L.; Carabineiro, S.A.C.; Bogdanchikova, N.; Cortés Corberán, V.; Pestryakov, A. Glycerol Oxidation over Supported Gold Catalysts: The Combined Effect of Au Particle Size and Basicity of Support. Processes 2020, 8, 1016.
  • Ruíz-Baltazar, Á.d.J.; Méndez-Lozano, N.; Larrañaga-Ordáz, D.; Reyes-López, S.Y.; Zamora Antuñano, M.A.; Pérez Campos, R. Magnetic Nanoparticles of Fe3O4 Biosynthesized by Cnicus benedictus Extract: Photocatalytic Study of Organic Dye Degradation and Antibacterial Behavior. Processes 2020, 8, 946.
  • Stefa, S.; Lykaki, M.; Fragkoulis, D.; Binas, V.; Pandis, P.K.; Stathopoulos, V.N.; Konsolakis, M. Effect of the Preparation Method on the Physicochemical Properties and the CO Oxidation Performance of Nanostructured CeO2/TiO2 Oxides. Processes 2020, 8, 847.
  • Morales-Torres, S.; Jirglová, H.; Pastrana-Martínez, L.M.; Maldonado-Hódar, F.J. Influence of Electrostatic Interactions During the Resorcinol-Formaldehyde Polymerization on the Characteristics of Mo-Doped Carbon Gels. Processes 2020, 8, 746.
  • Andrade, M.A.; Martins, L.M.D.R.S. Supported Palladium Nanocatalysts: Recent Findings in Hydrogenation Reactions. Processes 2020, 8, 1172.

References

  1. Astruc, D. Introduction: Nanoparticles in Catalysis. Chem. Rev. 2020, 120, 461–463. [Google Scholar] [CrossRef] [PubMed]
  2. Philippot, K.; Roucoux, A. (Eds.) Nanoparticles in Catalysis: Advances in Synthesis and Applications; Wiley: Weinheim, Germany, 2021. [Google Scholar]
  3. Munnik, P.; de Jongh, P.E.; de Jong, K.P. Recent Developments in the Synthesis of Supported Catalysts. Chem. Rev. 2015, 115, 6687–6718. [Google Scholar] [CrossRef] [PubMed]
  4. Khalil, M.; Kadja, G.T.M.; Ilmi, M.M. Advanced nanomaterials for catalysis: Current progress in fine chemical synthesis, hydrocarbon processing, and renewable energy. J. Ind. Eng. Chem. 2021, 93, 78–100. [Google Scholar] [CrossRef]
  5. Nanoscale engineering for sustainable catalysis. Nat. Nanotechnol. 2021, 16, 117. [CrossRef] [PubMed]
  6. Alshammari, A.; Kalevaru, V.N.; Martin, A. Bimetallic Catalysts Containing Gold and Palladium for Environmentally Important Reactions. Catalysts 2016, 6, 97. [Google Scholar] [CrossRef]
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Carabineiro, S.A.C. Advances in Supported Nanoparticle Catalysts. Processes 2024, 12, 365. https://doi.org/10.3390/pr12020365

AMA Style

Carabineiro SAC. Advances in Supported Nanoparticle Catalysts. Processes. 2024; 12(2):365. https://doi.org/10.3390/pr12020365

Chicago/Turabian Style

Carabineiro, Sónia Alexandra Correia. 2024. "Advances in Supported Nanoparticle Catalysts" Processes 12, no. 2: 365. https://doi.org/10.3390/pr12020365

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