Hemin-Modified SnO2/Metglas Electrodes for the Simultaneous Electrochemical and Magnetoelastic Sensing of H2O2
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Hemin/SnO2–Metglas Electrodes
2.3. Characterization of the Hemin/SnO2-Metglas Film Electrodes
2.4. Experimental Setup for MR and CV Measurements
2.5. Experimental Preparation and Procedure
3. Results and Discussion
3.1. X-ray Diffraction
3.2. FE-SEM Imaging of Surface Topography
3.3. Photoluminescence Properties
3.4. Fourier Transform Infrared Analysis
3.5. Electrochemical Behavior of Hemin/SnO2-Metglas and SnO2-Metglas Electrodes
3.6. Electrocatalytic Behavior of H2O2 at the Hemin/SnO2-Metglas Electrode
3.7. Amperometric Sensing of H2O2
3.8. Magnetic Resonance Behavior of the Sensor
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Electrode | Preparation | Particle Size (nm) | Thickness (μm) | Insulating Region | Ref. |
---|---|---|---|---|---|
Hemin/SnO2-ITO/PET | Low temperature Hydrothermal method | 20–70 | 4 | At +0.2 V and more positive biases | [32] |
Hemin-ZnO-Metglas | Hydrothermal method/sintering | 11–32 | 1 | none | [43] |
Hemin/TiO2-FTO 1 | Hydrolysis/sol-gel/sintering | 10–15 | 2 | At −0.3 V and more positive biases | [37] |
Hemin/TiO2-GCE 2 electrode | Flame synthesis technique | 10–50 | 10 | none | [28] |
Cyt-c 3/SnO2/FTO Hb 4/SnO2/FTO | Sol-gel/sintering | 15–20 | 4 | At +0.2 V and more positive biases | [50] |
Cyt-c/TiO2/FTO Cyt-c/ZnO/FTO | Sol-gel/sintering | 10–20 | 4 | At −0.15 V and more positive biases | [44] |
Hemin/SnO2-Metglas | Low temperature Hydrothermal method | 20–70 | 11 | none | This work |
Electrode | Method | Linear Range (M) | LOD (M) | Ref. |
---|---|---|---|---|
Hemin/SnO2-ITO/PET | CV | 1.5 × 10−6–90 × 10−6 | 1.5 × 10−6 | [32] |
Hb/ZnO-Metglas | CV & MR | 25 × 10−6–350 × 10−6 | 25 × 10−6–50 × 10−6 | [43] |
Hemin-graphene nano-sheets (H-GNs)/gold nano-particles (AuNPs) | CV & Amperometry | 0.3 × 10−6–1.8 × 10−3 | 0.11 × 10−6 | [58] |
Hemin-TiO2 modified electrode | CV & Amperometry | 3.0 × 10−7–4.7 × 10−4 | 7.2 × 10−8 | [28] |
Hemin-GCE | CV | 0–170 × 10−6 | 31.6 × 10−6 | [59] |
ITO/NiO/Hemin | CV | 0.5 × 10−6–500 × 10−6 | 10−7 | [26] |
Hemin/SnO2-Metglas | CV & MR | 2 × 10−6–90 × 10−6 | 1.6 × 10−7 | This work |
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Samourgkanidis, G.; Nikolaou, P.; Gkovosdis-Louvaris, A.; Sakellis, E.; Blana, I.M.; Topoglidis, E. Hemin-Modified SnO2/Metglas Electrodes for the Simultaneous Electrochemical and Magnetoelastic Sensing of H2O2. Coatings 2018, 8, 284. https://doi.org/10.3390/coatings8080284
Samourgkanidis G, Nikolaou P, Gkovosdis-Louvaris A, Sakellis E, Blana IM, Topoglidis E. Hemin-Modified SnO2/Metglas Electrodes for the Simultaneous Electrochemical and Magnetoelastic Sensing of H2O2. Coatings. 2018; 8(8):284. https://doi.org/10.3390/coatings8080284
Chicago/Turabian StyleSamourgkanidis, Georgios, Pavlos Nikolaou, Andreas Gkovosdis-Louvaris, Elias Sakellis, Ioanna Maria Blana, and Emmanuel Topoglidis. 2018. "Hemin-Modified SnO2/Metglas Electrodes for the Simultaneous Electrochemical and Magnetoelastic Sensing of H2O2" Coatings 8, no. 8: 284. https://doi.org/10.3390/coatings8080284