Poisoning Effect of SO2 on Honeycomb Cordierite-Based Mn–Ce/Al2O3Catalysts for NO Reduction with NH3 at Low Temperature
Abstract
:1. Introduction
2. Materials and Methods
2.1. Catalyst Preparation
2.2. Catalytic Activity Evaluation
2.3. Catalyst Characterization
3. Results and Discussion
3.1. NH3-SCR Activity Results
3.2. Effects of SO2 and H2O on NO Removal Activity
3.3. Physico-Chemical Characterization of Honeycomb Cordierite-Based Mn–Ce/Al2O3 Catalysts
3.3.1. BET, SEM-EDS Mapping
3.3.2. XPS
3.3.3. TG-DTA
3.3.4. FT-IR Analysis
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Samples | Atomic Concentration (at %) | Surface Atomic Ratio (%) | |||||
---|---|---|---|---|---|---|---|
Mn | Ce | O | S | Ce3+/(Ce3+ + Ce4+) | Mn4+/(Mn2+ + Mn3+ + Mn4+) | O′/O′ + O′′ | |
F-Mn–Ce/Al2O3 | 7.31 | 2.49 | 55.21 | 0 | 11.6 | 35.6 | 15.8 |
S-Mn–Ce/Al2O3 | 4.05 | 1.99 | 66.75 | 3.01 | 12.7 | 26.74 | 30.5 |
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Wang, C.; Zhang, C.; Zhao, Y.; Yan, X.; Cao, P. Poisoning Effect of SO2 on Honeycomb Cordierite-Based Mn–Ce/Al2O3Catalysts for NO Reduction with NH3 at Low Temperature. Appl. Sci. 2018, 8, 95. https://doi.org/10.3390/app8010095
Wang C, Zhang C, Zhao Y, Yan X, Cao P. Poisoning Effect of SO2 on Honeycomb Cordierite-Based Mn–Ce/Al2O3Catalysts for NO Reduction with NH3 at Low Temperature. Applied Sciences. 2018; 8(1):95. https://doi.org/10.3390/app8010095
Chicago/Turabian StyleWang, Chengzhi, Cheng Zhang, Yonggang Zhao, Xin Yan, and Peng Cao. 2018. "Poisoning Effect of SO2 on Honeycomb Cordierite-Based Mn–Ce/Al2O3Catalysts for NO Reduction with NH3 at Low Temperature" Applied Sciences 8, no. 1: 95. https://doi.org/10.3390/app8010095