N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México
Abstract
:1. Introduction
2. Materials and Methods
2.1. X-Ray Diffraction (XRD) and Energy-Dispersive X-Ray Spectroscopy (EDS)
2.2. N2 Adsorption
2.3. CO2 Adsorption
2.4. Data Analysis
3. Results and Discussion
3.1. Crystalline Phases and Chemical Composition
3.2. N2 Adsorption
3.3. CO2 Adsorption
4. Conclusions
Author Contributions
Conflicts of Interest
References
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Compound | SJA1 | SJA2 | SJA3 | SJA4 |
---|---|---|---|---|
Na2O | 1.685 | 2.042 | 0.517 | 1.685 |
MgO | 0.000 | 0.000 | 4.488 | 2.338 |
Al2O3 | 14.191 | 14.455 | 10.575 | 15.211 |
SiO2 | 32.173 | 44.346 | 30.148 | 30.227 |
K2O | 0.258 | 0.295 | 0.000 | 0.000 |
CaO | 1.994 | 4.869 | 0.541 | 1.758 |
TiO2 | 0.000 | 1.043 | 0.323 | 0.167 |
Fe2O3 | 4.046 | 3.710 | 7.058 | 3.408 |
SiO2/AlO3 Ratio | 2.267 | 3.068 | 2.851 | 1.987 |
Sample | AsBET m2·g−1 | R | CBET | BET p/p0 Plot | VΣ cm3·g−1 |
---|---|---|---|---|---|
SJA1 | 25 | 0.999 | 240 | 0.010–0.131 | 0.033 |
SJA2 | 22.2 | 0.999 | 265 | 0.010–0.164 | 0.023 |
SJA3 | 6.73 | 0.998 | 33.24 | 0.084–0.189 | 0.034 |
SJA4 | 45.9 | 0.999 | 270 | 0.010–0.189 | 0.064 |
Muestra | T (K) | Freundlich | Langmuir | ||||
---|---|---|---|---|---|---|---|
R | n | KF | R | am | KL | ||
SJA1 | 573 | 0.997 | 1.357 | 0.0107 | 0.981 | 0.152 | 0.072 |
523 | 0.999 | 1.398 | 0.011 | 0.994 | 0.149 | 0.077 | |
473 | 0.997 | 1.598 | 0.0157 | 0.972 | 0.11 | 0.2 | |
SJA2 | 573 | 0.999 | 1.443 | 0.0056 | 0.994 | 0.092 | 0.046 |
523 | 0.999 | 1.47 | 0.0062 | 0.984 | 0.079 | 0.067 | |
473 | 0.999 | 1.497 | 0.0064 | 0.974 | 0.067 | 0.088 | |
SJA4 | 573 | 0.998 | 1.691 | 0.0119 | 0.992 | 0.099 | 0.098 |
523 | 0.999 | 1.739 | 0.0128 | 0.979 | 0.092 | 0.121 | |
473 | 0.998 | 1.84 | 0.0148 | 0.985 | 0.088 | 0.158 |
Muestra | T (K) | −ΔH (kJ·mol−1) | −ΔG (kJ·mol−1) | −ΔU (kJ·mol−1) | ΔS (J·K−1·mol−1) |
---|---|---|---|---|---|
SJA1 | 573 | 4.505 | 71.524 | 11.491 | 116.962 |
483 | 55.797 | 106.193 | |||
453 | 51.148 | 102.964 | |||
SJA2 | 573 | 2.904 | 69.190 | 6.648 | 115.682 |
483 | 55.237 | 108.352 | |||
453 | 50.597 | 105.283 | |||
SJA4 | 573 | 8.037 | 70.621 | 10.394 | 109.223 |
483 | 55.754 | 96.413 | |||
453 | 50.911 | 102.798 |
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Quiroz-Estrada, K.; Hernández-Espinosa, M.Á.; Rojas, F.; Portillo, R.; Rubio, E.; López, L. N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México. Minerals 2016, 6, 73. https://doi.org/10.3390/min6030073
Quiroz-Estrada K, Hernández-Espinosa MÁ, Rojas F, Portillo R, Rubio E, López L. N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México. Minerals. 2016; 6(3):73. https://doi.org/10.3390/min6030073
Chicago/Turabian StyleQuiroz-Estrada, Karla, Miguel Ángel Hernández-Espinosa, Fernando Rojas, Roberto Portillo, Efraín Rubio, and Lucía López. 2016. "N2 and CO2 Adsorption by Soils with High Kaolinite Content from San Juan Amecac, Puebla, México" Minerals 6, no. 3: 73. https://doi.org/10.3390/min6030073