Two-Sided Surface Oxidized Cellulose Membranes Modified with PEI: Preparation, Characterization and Application for Dyes Removal
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Preparation of the RC Membranes
2.3. Preparation of the TEMPO–Oxidized RC Membranes
2.4. Preparation of Aminated TORC Membranes
2.5. Characterization of the Functionalized TORC Membranes
2.6. Batch Adsorption Experiments
2.7. Adsorption Isotherm and Kinetic Model
3. Results and Discussion
3.1. Characterization of the Modified RC Membranes
3.2. Adsorption Properties of the RC and PEI-TORC Membranes
3.3. Effect of the pH on Adsorption
3.4. Effect of the Initial Dye Concentration and the Adsorption Isotherm
3.5. Effect of the Contact Time and the Adsorption Kinetics
3.6. Reusability
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample | C (%) | O (%) | H (%) | N (%) |
---|---|---|---|---|
RC | 41.02 | 49.11 | 9.87 | 0 |
TORC | 39.64 | 51.29 | 9.07 | 0 |
PEI-TORC | 41.98 | 45.91 | 8.24 | 3.87 |
Langmuir Model | Freundlich Model | ||||||
---|---|---|---|---|---|---|---|
pH | Dyes | Kl (L·mg−1) | qmax (mg·g−1) | R2 | n | Kf (mg·g−1) | R2 |
6.8 | XO | 0.018 | 240.96 | 0.9981 | 2.89 | 25.28 | 0.9465 |
MB | 0.024 | 144.09 | 0.9987 | 3.12 | 18.64 | 0.8902 | |
4.6 | XO | 0.030 | 420.17 | 0.9995 | 2.56 | 39.30 | 0.8922 |
MB | 0.031 | 76.57 | 0.9998 | 3.36 | 11.90 | 0.8170 |
Pseudo-First Order Model | Pseudo-Second Order Model | ||||||
---|---|---|---|---|---|---|---|
pH | Dyes | K1 (g·mg−1 min−1) | qe (mg·g−1) | R2 | K2 (g·mg−1·min−1) | qe (mg·g−1) | R2 |
6.8 | XO | 0.049 | 5.16 | 0.9753 | 0.0092 | 24.75 | 0.9999 |
MB | 0.092 | 13.01 | 0.9954 | 0.017 | 22.16 | 0.9996 | |
4.6 | XO | 0.072 | 5.09 | 0.9144 | 0.028 | 25.03 | 0.9999 |
MB | 0.054 | 7.61 | 0.9631 | 0.014 | 17.84 | 0.9997 |
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Wang, W.; Bai, Q.; Liang, T.; Bai, H.; Liu, X. Two-Sided Surface Oxidized Cellulose Membranes Modified with PEI: Preparation, Characterization and Application for Dyes Removal. Polymers 2017, 9, 455. https://doi.org/10.3390/polym9090455
Wang W, Bai Q, Liang T, Bai H, Liu X. Two-Sided Surface Oxidized Cellulose Membranes Modified with PEI: Preparation, Characterization and Application for Dyes Removal. Polymers. 2017; 9(9):455. https://doi.org/10.3390/polym9090455
Chicago/Turabian StyleWang, Wei, Qian Bai, Tao Liang, Huiyu Bai, and Xiaoya Liu. 2017. "Two-Sided Surface Oxidized Cellulose Membranes Modified with PEI: Preparation, Characterization and Application for Dyes Removal" Polymers 9, no. 9: 455. https://doi.org/10.3390/polym9090455