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Polymers 2018, 10(6), 570; https://doi.org/10.3390/polym10060570

Preparation of Functionalized Magnetic Fe3O4@Au@polydopamine Nanocomposites and Their Application for Copper(II) Removal

Department of Chemical Engineering and Materials, Ocean College, Minjiang University, Fuzhou 350108, China
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Received: 7 April 2018 / Revised: 19 May 2018 / Accepted: 21 May 2018 / Published: 23 May 2018
(This article belongs to the Special Issue Core-Shell Structured Polymers)
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Abstract

Polydopamine (PDA) displays many striking properties of naturally occurring melanin in optics, electricity, and biocompatibility. Another valuable feature of polydopamine lies in its chemical structure that incorporates many functional groups such as amine, catechol and imine. In this study, a nanocomposite of magnetic Fe3O4@Au@polydopamine nanopaticles (Fe3O4@Au@ PDA MNPs) was synthesized. Carboxyl functionalized Fe3O4@Au nanoparticles (NPs) were successfully embedded in a layer of PDA through dopamine oxypolymerization in alkaline solution. Through the investigation of adsorption behavior to Cu(II), combined with high sensitive electrochemical detection, the as-prepared magnetic nanocomposites (MNPs) have been successfully applied in the separation and analysis of Cu(II). The experimental parameters of temperature, Cu(II) concentration and pH were optimized. Results showed that the as-prepared MNPs can reach saturation adsorption after adsorbing 2 h in neutral environment. Furthermore, the as-prepared MNPs can be easily regenerated by temperature control and exhibits a good selectivity compared to other metal ions. The prepared Fe3O4@Au@PDA MNPs are expected to act as a kind of adsorbent for Cu(II) deep removal from contaminated waters. View Full-Text
Keywords: magnetic nanocomposites; copper(II); polydopamine; Fe3O4@Au nanoparticles magnetic nanocomposites; copper(II); polydopamine; Fe3O4@Au nanoparticles
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Li, Y.; Huang, L.; He, W.; Chen, Y.; Lou, B. Preparation of Functionalized Magnetic Fe3O4@Au@polydopamine Nanocomposites and Their Application for Copper(II) Removal. Polymers 2018, 10, 570.

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