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Crystals 2015, 5(3), 405-417; doi:10.3390/cryst5030405

Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion

Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Magdeburg 39106, Germany
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Academic Editor: Thomas M. Klapötke
Received: 31 July 2015 / Revised: 27 August 2015 / Accepted: 8 September 2015 / Published: 18 September 2015
(This article belongs to the Special Issue Energetic Materials)
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Abstract

Two new potentially energetic salts comprising the 5,5'-azotetrazolate dianion have been prepared and structurally characterized. The new azotetrazolates are tetraphenylphosphonium-5,5'-azotetrazolate (1) and 1H-1,2,4-triazole-1-carboxamidine-5,5'-azotetrazolate (2). The crystal structures of both compounds have been determined by single-crystal X-ray diffraction and their energetic properties have been tested. Due to its high nitrogen-content of 73.14%, compound 2 was found to be significantly impact-sensitive. View Full-Text
Keywords: energetic salts; azotetrazolate; phosphonium; 1H-1,2,4-triazole-1-carboxamidine; hydrogen bonds energetic salts; azotetrazolate; phosphonium; 1H-1,2,4-triazole-1-carboxamidine; hydrogen bonds
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Deblitz, R.; Hrib, C.G.; Edelmann, F.T. Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion. Crystals 2015, 5, 405-417.

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