Crystals 2012, 2(2), 327-337; doi:10.3390/cryst2020327
Article

Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs

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Received: 22 March 2012; in revised form: 11 April 2012 / Accepted: 11 April 2012 / Published: 24 April 2012
(This article belongs to the Special Issue Molecular Conductors)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Oxidation of 3,4-ethylenedithio-3'-iodo-tetrathiafulvalene (EDT-TTF-I) and 3,4-ethylenedithio-3',4'-diiodo-tetrathiafulvalene (EDT-TTF-I2) with DDQ afforded two different salts formulated as (EDT-TTF-I)(DDQ) and (EDT-TTF-I2)2(DDQ)·(CH3CN), both characterized with a full charge transfer to the DDQ acceptor moiety and by short and linear halogen bonding interactions between the iodine atom as halogen bond donor, and the carbonyl oxygen or the nitrile nitrogen atoms of reduced DDQ.
Keywords: charge-transfer salts; halogen bonding; tetrathiafulvalene; crystal structure; iodine; magnetism
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MDPI and ACS Style

Lieffrig, J.; Jeannin, O.; Shin, K.-S.; Auban-Senzier, P.; Fourmigué, M. Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs. Crystals 2012, 2, 327-337.

AMA Style

Lieffrig J, Jeannin O, Shin K-S, Auban-Senzier P, Fourmigué M. Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs. Crystals. 2012; 2(2):327-337.

Chicago/Turabian Style

Lieffrig, Julien; Jeannin, Olivier; Shin, Kyoung-Soon; Auban-Senzier, Pascale; Fourmigué, Marc. 2012. "Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs." Crystals 2, no. 2: 327-337.

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