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Catalysts 2017, 7(7), 206; doi:10.3390/catal7070206

Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline

Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
These authors contributed equally to this work.
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Received: 7 May 2017 / Revised: 21 June 2017 / Accepted: 23 June 2017 / Published: 7 July 2017
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Abstract

Cerium coordination polymer (CeCP) was synthesized with 1,3,5-benzenetricarboxylic acid as the ligand. By using the carboxyl groups on the surface of CeCP as the anchors, platinum nanoparticles were formed on CeCP forming the composite CeCP@Pt. The composite was characterized by measuring TEM images, and EDS and XPS spectra. CeCP@Pt was used to catalyze the oxidation of 3,3,5,5-tetramethylbenzidine in the presence of H2O2. The activity assay demonstrated that CeCP@Pt exhibited an activity similar to that of horseradish peroxidase, but with a much higher activity. CeCP@Pt was utilized to detect nitroaniline, being able to detect trace amount of nitroaniline (>3.125 × 10−4 mg/mL). View Full-Text
Keywords: Cerium coordination polymer; peroxidase mimics; Pt; nitroaniline Cerium coordination polymer; peroxidase mimics; Pt; nitroaniline
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Wang, X.; Zheng, K.; Ji, P. Cerium Coordination Polymer Based Composite Mimicking Peroxidase for Detection of Nitroaniline. Catalysts 2017, 7, 206.

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