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Catalysts 2013, 3(4), 794-810; doi:10.3390/catal3040794
Review

Palladium-Catalyzed Intermolecular Oxidative Amination of Alkenes with Amines, Using Molecular Oxygen as Terminal Oxidant

*  and
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
* Author to whom correspondence should be addressed.
Received: 25 July 2013 / Revised: 29 September 2013 / Accepted: 8 October 2013 / Published: 16 October 2013
(This article belongs to the Special Issue Palladium Catalysts for Cross-Coupling Reaction)
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Abstract

In this review, we summarize recent progress from our group with regard to Pd-catalyzed oxidative amination of alkenes with amines. Intermolecular oxidative amination of alkenes with secondary anilines was induced using a palladium-complex catalyst combined with molybdovanadophosphate as a co-catalyst under dioxygen, leading to allylic amines and enamines in good yields with high selectivities. The reaction proceeded efficiently, using molecular oxygen as the terminal oxidant. In addition, palladium-catalyzed oxidative amination of alkenes with anilines as primary amines was achieved using molecular oxygen as the sole oxidant, producing (Z)-N-alkenyl-substituted anilines in high yields.
Keywords: amination; enamine; allylic amine; molybdovanadophosphate; oxidative coupling; alkenes amination; enamine; allylic amine; molybdovanadophosphate; oxidative coupling; alkenes
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Obora, Y.; Ishii, Y. Palladium-Catalyzed Intermolecular Oxidative Amination of Alkenes with Amines, Using Molecular Oxygen as Terminal Oxidant. Catalysts 2013, 3, 794-810.

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