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Catalysts 2013, 3(4), 839-852; doi:10.3390/catal3040839
Article

Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents

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Received: 9 August 2013; in revised form: 25 September 2013 / Accepted: 8 October 2013 / Published: 22 October 2013
(This article belongs to the Special Issue Palladium Catalysts for Cross-Coupling Reaction)
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Abstract: A facile and efficient method for the synthesis of pentafluorophenyl- and related polyfluorophenyl-substituted porphyrins has been achieved via palladium-catalyzed cross-coupling reactions of brominated porphyrins with bis(polyfluorophenyl)zinc reagents. The reaction is applicable to a variety of free-base bromoporphyrins, their metal complexes, and a number of bis(polyfluorophenyl)zinc reagents.
Keywords: porphyrin; polyfluorophenylation; bis(polyfluorophenyl)zinc; palladium; cross-coupling porphyrin; polyfluorophenylation; bis(polyfluorophenyl)zinc; palladium; cross-coupling
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Sugita, N.; Hayashi, S.; Ishii, S.; Takanami, T. Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents. Catalysts 2013, 3, 839-852.

AMA Style

Sugita N, Hayashi S, Ishii S, Takanami T. Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents. Catalysts. 2013; 3(4):839-852.

Chicago/Turabian Style

Sugita, Noriaki; Hayashi, Satoshi; Ishii, Sawa; Takanami, Toshikatsu. 2013. "Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents." Catalysts 3, no. 4: 839-852.


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