Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution
Abstract
:1. Introduction
2. Results and Discussion
2.1. Bicarbonate Concentration
2.2. Dissolved Oxygen
2.3. Immersion Time
2.4. Surface Analysis
2.5. XRD Analyses
2.6. XPS Analyses
3. Experimental Section
3.1. Materials and Solutions
3.2. Electrochemical Test
3.3. Surface Analysis
3.4. X-ray Diffraction
3.5. X-ray Photoelectron Spectroscopy
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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DO (ppm) | Icorr (µA·cm−2) | Ecorr (mV) | ba (mV·dec−1) | −bc (mV·dec−1) |
---|---|---|---|---|
0.8 | 22.28 | −767.5 | 163.0 | 302.9 |
1 | 25.24 | −780.6 | 138.5 | 222.9 |
4 | 201.52 | −369.2 | 243.5 | 240.3 |
DO (ppm) | Rs (Ω·cm2) | Rct (Ω·cm2) | Qdl (F·cm−2) | n | Ra (Ω·cm2) | Qa (F·cm−2) |
---|---|---|---|---|---|---|
0.8 | 46.3 | 1015 | 1.76 × 10−3 | 0.77 | 440.04 | 5.9 × 10−4 |
1 | 53.8 | 874.7 | 1.18 × 10−3 | 0.66 | 90.49 | 1.39 × 10−3 |
4 | 63.5 | 104.7 | 6.88 × 10−3 | 0.59 | 33.04 | 3.75 × 10−3 |
Immersion Time (h) | Icorr (µA·cm−2) | Eb (mV) | Ecorr (mV) | ba (mV·dec−1) | −bc (mV·dec−1) |
---|---|---|---|---|---|
2 | 22.28 | −355.0 | −767.5 | 163.0 | 302.9 |
4 | 8.98 | −292.3 | −820.4 | 126.6 | 138.0 |
8 | 6.04 | −229.1 | −833.9 | 145.6 | 134.8 |
Immersion Time (h) | Rs (Ω·cm2) | Rct (Ω·cm2) | Qdl (F·cm−2) | n | Ra (Ω·cm2) | Qa (F·cm−2) |
---|---|---|---|---|---|---|
2 | 46.3 | 1015 | 1.76 × 10−3 | 0.77 | 440.04 | 5.9 × 10−4 |
4 | 30.5 | 1370 | 1.65 × 10−3 | 1 | 804.0 | 5.04 × 10−4 |
8 | 41.6 | 2700 | 7.28 × 10−4 | 0.82 | 618.6 | 5.83 × 10−4 |
C | Si | Mn | Cr | Cu | Ni | Fe |
---|---|---|---|---|---|---|
0.20 | 0.32 | 0.79 | 0.01 | 0.01 | 0.01 | Bal |
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Eyu, G.D.; Will, G.; Dekkers, W.; MacLeod, J. Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution. Materials 2016, 9, 748. https://doi.org/10.3390/ma9090748
Eyu GD, Will G, Dekkers W, MacLeod J. Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution. Materials. 2016; 9(9):748. https://doi.org/10.3390/ma9090748
Chicago/Turabian StyleEyu, Gaius Debi, Geoffrey Will, Willem Dekkers, and Jennifer MacLeod. 2016. "Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution" Materials 9, no. 9: 748. https://doi.org/10.3390/ma9090748