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Materials 2012, 5(9), 1722-1739; doi:10.3390/ma5091722
Article

Hyperpolarized Xenon Nuclear Magnetic Resonance (NMR) of Building Stone Materials

 and *
Received: 12 July 2012; in revised form: 27 August 2012 / Accepted: 14 September 2012 / Published: 24 September 2012
(This article belongs to the Special Issue NMR in Materials Science)
Download PDF [1039 KB, uploaded 24 September 2012]
Abstract: We have investigated several building stone materials, including minerals and rocks, using continuous flow hyperpolarized xenon (CF-HP) NMR spectroscopy to probe the surface composition and porosity. Chemical shift and line width values are consistent with petrographic information. Rare upfield shifts were measured and attributed to the presence of transition metal cations on the surface. The evolution of freshly cleaved rocks exposed to the atmosphere was also characterized. The CF-HP 129Xe NMR technique is non-destructive and it could complement currently used techniques, like porosimetry and microscopy, providing additional information on the chemical nature of the rock surface and its evolution.
Keywords: 129Xe NMR; hyperpolarization; continuous flow; adsorption; diffusion; petrography; rocks; weathering; porosity 129Xe NMR; hyperpolarization; continuous flow; adsorption; diffusion; petrography; rocks; weathering; porosity
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Mauri, M.; Simonutti, R. Hyperpolarized Xenon Nuclear Magnetic Resonance (NMR) of Building Stone Materials. Materials 2012, 5, 1722-1739.

AMA Style

Mauri M, Simonutti R. Hyperpolarized Xenon Nuclear Magnetic Resonance (NMR) of Building Stone Materials. Materials. 2012; 5(9):1722-1739.

Chicago/Turabian Style

Mauri, Michele; Simonutti, Roberto. 2012. "Hyperpolarized Xenon Nuclear Magnetic Resonance (NMR) of Building Stone Materials." Materials 5, no. 9: 1722-1739.


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