Sensors 2008, 8(11), 7085-7096; doi:10.3390/s8117085
Article

Electrochemical Performance of a Carbon Nanotube/La-Doped TiO2 Nanocomposite and its Use for Preparation of an Electrochemical Nicotinic Acid Sensor

1,* email, 1,* email and 2email
1 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, P.R. China, 430070 2 School of Materials Science Engineering, Wuhan Institute of Technology, Wuhan, Hubei, P.R. China 430073
* Authors to whom correspondence should be addressed.
Received: 1 September 2008; in revised form: 22 September 2008 / Accepted: 27 September 2008 / Published: 7 November 2008
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Abstract: A carbon nanotube/La-doped TiO2 (La-TiO2) nanocomposite (CLTN) was prepared by a procedure similar to a complex/adsorption process. Scanning electron microscopy (SEM) images show that the La-TiO2 distributes on the carbon nanotube walls. The CLTN was mixed with paraffin to form a CLTN paste for the CLTN paste electrode (CLTNPE). The electrochemical characteristics of CLTNPE were compared with that of conventional carbon electrodes such as the carbon paste electrode (CPE) and glass carbon electrode (GC). The CLTNPE exhibits electrochemical activity and was used to investigate the electrochemistry of nicotinic acid (NA). The modified electrode has a strong electrocatalytic effect on the redox of NA. The cyclic voltammetry (CV) redox potential of NA at the CLTNPE is 320 mV. The oxidation process of NA on the CLTNPE is pH dependent. A sensitive chronoamperometric response for NA was obtained covering a linear range from 1.0×10-6 mol·L-1 to 1.2×10-4 mol·L-1, with a detection limit of 2.7×10-7 mol·L-1. The NA sensor displays a remarkable sensitivity and stability. The mean recovery of NA in the human urine is 101.8%, with a mean variation coefficient (RSD) of 2.6%.
Keywords: Carbon nanotube/La-TiO2 nanocomposite (CLTN); sensor; nicotinic acid (NA)

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MDPI and ACS Style

Wu, J.; Liu, H.; Lin, Z. Electrochemical Performance of a Carbon Nanotube/La-Doped TiO2 Nanocomposite and its Use for Preparation of an Electrochemical Nicotinic Acid Sensor. Sensors 2008, 8, 7085-7096.

AMA Style

Wu J, Liu H, Lin Z. Electrochemical Performance of a Carbon Nanotube/La-Doped TiO2 Nanocomposite and its Use for Preparation of an Electrochemical Nicotinic Acid Sensor. Sensors. 2008; 8(11):7085-7096.

Chicago/Turabian Style

Wu, Jing; Liu, Hanxing; Lin, Zhidong. 2008. "Electrochemical Performance of a Carbon Nanotube/La-Doped TiO2 Nanocomposite and its Use for Preparation of an Electrochemical Nicotinic Acid Sensor." Sensors 8, no. 11: 7085-7096.

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