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Synergistic Effects in the Gas Sensitivity of Polypyrrole/Single Wall Carbon Nanotube Composites
School of Engineering Physics, Hanoi University of Science and Technology, No.1, Daicoviet, Hanoi 10000, Vietnam
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Received: 19 April 2012; in revised form: 24 May 2012 / Accepted: 25 May 2012 / Published: 8 June 2012
Abstract: Polypyrrole/single wall carbon nanotube composites were synthesized by in-situ chemical polymerization using pyrrole (PPy) as precursor and single wall carbon nanotubes (SWNTs) as additive component. Electron microscope images reveal that SWNTs component acts as nucleation sites for PPy growth in the form of spherical and cylindrical core-shell structures. The SWNTs/PPy core-shell results in thin n-p junctions which modify the PPy bandgap and reduce the work function of electrons. As a result of the strong coupling, Raman and IR spectra show that the PPy undergoes a transition from polaron to bipolaron state, i.e., indicating an increase in the conductivity. In the UV-Vis spectra, the 340 nm adsorption band (π*-π transition) exhibits a red shift, while the 460 nm adsorption band (bipolaron transition) experiences a blue shift indicating a change in electronic structure and a relocation of polaron levels in the band gap of PPy. The modification in PPy electronic structure brings in a synergistic effect in sensing feature. Upon exposure to oxygen (an oxidizing agent) and NH3 gas (a reducing agent), the PPy/SWNTs nanocomposite shows an enhancement in sensitivity exceeding ten folds in comparison with those of PPy or SWNTs.
Keywords: PPy; single wall carbon nanotube; nanocomposite; gas sensor
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Huyen, D.N.; Tung, N.T.; Vinh, T.D.; Thien, N.D. Synergistic Effects in the Gas Sensitivity of Polypyrrole/Single Wall Carbon Nanotube Composites. Sensors 2012, 12, 7965-7974.
Huyen DN, Tung NT, Vinh TD, Thien ND. Synergistic Effects in the Gas Sensitivity of Polypyrrole/Single Wall Carbon Nanotube Composites. Sensors. 2012; 12(6):7965-7974.
Huyen, Duong Ngoc; Tung, Nguyen Trong; Vinh, Tran Dinh; Thien, Nguyen Duc. 2012. "Synergistic Effects in the Gas Sensitivity of Polypyrrole/Single Wall Carbon Nanotube Composites." Sensors 12, no. 6: 7965-7974.