AbstractThe two geometric isomers of 2-(tert-butyl)-4-phenyloxetane have, for the first time, been prepared starting from the commercially available 4,4-dimethyl-1-phenylpentane-1,3-dione. The latter was reduced with NaBH4 to give a mixture of diastereomeric syn and anti diols which were then stereospecifically cyclized into the corresponding oxetanes with an overall yield for the two steps of 69.6%. The newly synthesized stereoisomeric four-membered oxygenated heterocycles were separated by column chromatography on silica gel and fully spectroscopically characterized. View Full-Text
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Perna, F.M.; Vitale, P.; Summa, S.; Capriati, V. 2-(tert-Butyl)-4-phenyloxetane. Molbank 2017, 2017, M930.
Perna FM, Vitale P, Summa S, Capriati V. 2-(tert-Butyl)-4-phenyloxetane. Molbank. 2017; 2017(1):M930.Chicago/Turabian Style
Perna, Filippo M.; Vitale, Paola; Summa, Simona; Capriati, Vito. 2017. "2-(tert-Butyl)-4-phenyloxetane." Molbank 2017, no. 1: M930.
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