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Molbank 2010, 2010(3), M696; doi:10.3390/M696

Short Note

Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)­(diphenyl)phosphine]­ruthenium(II) Complex

Ismail Warad

Department of Chemistry, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia

Received: 21 July 2010 / Accepted: 10 September 2010 / Published: 17 September 2010

Download PDF Full-Text [125 KB, uploaded 17 September 2010 11:24 CEST]

Abstract: Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)­(diphenyl)­phos­phine]­­ruthenium(II) complex Cl₂Ru(h¹-Ph₂PCH₂CH₂OCH₃)₂(C₁₀H₁₀N₂) has been obtained by reaction of equimolar amounts of Cl₂Ru(P^ÇO)₂ complex 2 with one equivalent of 2,3-naphthalenediamine as co-ligand in very good yield. The structure of this new complex 3 was confirmed by elemental analysis, IR, ³¹P-NMR ¹H-NMR, ¹³C-NMR, UV-visible spectroscopy and FAB-MS.

Keywords: ruthenium(II) complexes; Hemilabile ether-phosphine; diamine ligand

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  3D structure generated by CORINA by Molecular Networks.

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